Methoxymethylation of Alcohols Catalyzed by Sulfated Metal Oxides
Тип публикации: Journal Article
Дата публикации: 2003-06-06
scimago Q2
wos Q3
БС2
SJR: 0.539
CiteScore: 4.9
Impact factor: 2.4
ISSN: 1011372X, 1572879X
General Chemistry
Catalysis
Краткое описание
More acidic sulfated metal oxides (SMO) such as SO4 2-/ZrO2 and SO4 2-/TiO2 catalyzed the methoxymethylation of alcohols with dimethoxymethane at ambient temperature to achieve a product yield of greater than 90% within a few hours. The reaction displayed a significant steric effect on the product yield with a preferential order of primary alcohol > secondary alcohol ≫ tertiary alcohol. The observed steric effect might result from the repulsion between the bulky alkyl group in the alcohol and the two methoxy groups in the protonated dimethoxymethane (oxonium ion).
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ГОСТ
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Lin C. Methoxymethylation of Alcohols Catalyzed by Sulfated Metal Oxides // Catalysis Letters. 2003. Vol. 87. No. 3/4. pp. 253-256.
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Lin C. Methoxymethylation of Alcohols Catalyzed by Sulfated Metal Oxides // Catalysis Letters. 2003. Vol. 87. No. 3/4. pp. 253-256.
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TY - JOUR
DO - 10.1023/a:1023472029190
UR - https://doi.org/10.1023/a:1023472029190
TI - Methoxymethylation of Alcohols Catalyzed by Sulfated Metal Oxides
T2 - Catalysis Letters
AU - Lin, Chiu-Hsun
PY - 2003
DA - 2003/06/06
PB - Springer Nature
SP - 253-256
IS - 3/4
VL - 87
SN - 1011-372X
SN - 1572-879X
ER -
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@article{2003_Lin,
author = {Chiu-Hsun Lin},
title = {Methoxymethylation of Alcohols Catalyzed by Sulfated Metal Oxides},
journal = {Catalysis Letters},
year = {2003},
volume = {87},
publisher = {Springer Nature},
month = {jun},
url = {https://doi.org/10.1023/a:1023472029190},
number = {3/4},
pages = {253--256},
doi = {10.1023/a:1023472029190}
}
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MLA
Скопировать
Lin, Chiu-Hsun. “Methoxymethylation of Alcohols Catalyzed by Sulfated Metal Oxides.” Catalysis Letters, vol. 87, no. 3/4, Jun. 2003, pp. 253-256. https://doi.org/10.1023/a:1023472029190.