Role of the V(V)/1O2 complex in oxidative reactions in the H2 O2 /V(V)/AcOH system: Oxidation of alkenes and anthracenes
Тип публикации: Journal Article
Дата публикации: 2001-01-01
scimago Q3
wos Q4
БС2
SJR: 0.260
CiteScore: 1.9
Impact factor: 1.4
ISSN: 00231584, 16083210
General Chemistry
Catalysis
Computer Science Applications
Modeling and Simulation
Краткое описание
Anthracene and its alkyl derivatives undergo oxidation in the V(V)/H2O2/AcOH system via a nonradical mechanism through the intermediate formation of the vanadium(V) complex with singlet dioxygen as a ligand. The 1O2molecule is transferred from this complex to an unsaturated substrate. The free singlet dioxygen 1O2(1Δ g ) is almost inactive toward anthracene in AcOH solution. Consequently, the vanadium(V) complex with singlet dioxygen is the only oxidant species active in the reaction. The ratio between the rate constant of the reaction of this complex with 2-ethylanthracene and the rate constant of its deactivation is an order of magnitude greater than the ratio between the rate constant of the reaction of dissolved free singlet dioxygen with the same substrate and the rate constant of its deactivation (physical quenching).
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Gekhman A. E. et al. Role of the V(V)/1O2 complex in oxidative reactions in the H2O2/V(V)/AcOH system: Oxidation of alkenes and anthracenes // Kinetics and Catalysis. 2001. Vol. 42. No. 4. pp. 496-505.
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Gekhman A. E., Amelichkina G. E., Moiseeva N. I., Vargaftik M., Moiseev I. I. Role of the V(V)/1O2 complex in oxidative reactions in the H2O2/V(V)/AcOH system: Oxidation of alkenes and anthracenes // Kinetics and Catalysis. 2001. Vol. 42. No. 4. pp. 496-505.
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TY - JOUR
DO - 10.1023/A:1010569405343
UR - http://link.springer.com/10.1023/A:1010569405343
TI - Role of the V(V)/1O2 complex in oxidative reactions in the H2O2/V(V)/AcOH system: Oxidation of alkenes and anthracenes
T2 - Kinetics and Catalysis
AU - Gekhman, A E
AU - Amelichkina, G E
AU - Moiseeva, N I
AU - Vargaftik, M.N.
AU - Moiseev, I. I.
PY - 2001
DA - 2001/01/01
PB - Springer Nature
SP - 496-505
IS - 4
VL - 42
SN - 0023-1584
SN - 1608-3210
ER -
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@article{2001_Gekhman,
author = {A E Gekhman and G E Amelichkina and N I Moiseeva and M.N. Vargaftik and I. I. Moiseev},
title = {Role of the V(V)/1O2 complex in oxidative reactions in the H2O2/V(V)/AcOH system: Oxidation of alkenes and anthracenes},
journal = {Kinetics and Catalysis},
year = {2001},
volume = {42},
publisher = {Springer Nature},
month = {jan},
url = {http://link.springer.com/10.1023/A:1010569405343},
number = {4},
pages = {496--505},
doi = {10.1023/A:1010569405343}
}
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MLA
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Gekhman, A. E., et al. “Role of the V(V)/1O2 complex in oxidative reactions in the H2O2/V(V)/AcOH system: Oxidation of alkenes and anthracenes.” Kinetics and Catalysis, vol. 42, no. 4, Jan. 2001, pp. 496-505. http://link.springer.com/10.1023/A:1010569405343.