Springer Nature
High Energy Chemistry
,  volume 35 ,  issue 6 ,  pages 399-403

Positive hole transfer upon irradiation of frozen alkylbenzene solutions in freonic matrices at 77 K

Publication type: Journal Article
Publication date: 2001-11-01
Springer Nature
scimago Q4
wos Q4
SJR: 0.178
CiteScore: 0.9
Impact factor: 0.6
ISSN: 00181439, 16083148
Physical and Theoretical Chemistry
Abstract
The process of positive hole transfer between alkylbenzene molecules of various structures occurring upon irradiation in electron-scavenging (freonic) matrices at 77 K was studied by ESR. The factors controlling the efficiency and direction of this process were analyzed. In the case of the ethylbenzene–toluene pair, it was shown that the direction of hole transfer depends on the conformation of the ethylbenzene radical cation. If the conformation effects are absent, the hole transfer occurs in accordance with the gas-phase ionization potentials (IP) and appears to be efficient, provided that the difference in the IP values is greater than 0.3 eV.
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GOST |
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GOST Copy
Egorov A. V. et al. Positive hole transfer upon irradiation of frozen alkylbenzene solutions in freonic matrices at 77 K // High Energy Chemistry. 2001. Vol. 35. No. 6. pp. 399-403.
GOST all authors (up to 50) Copy
Egorov A. V., Zezin A. A., Feldman V. I. Positive hole transfer upon irradiation of frozen alkylbenzene solutions in freonic matrices at 77 K // High Energy Chemistry. 2001. Vol. 35. No. 6. pp. 399-403.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1023/A:1012582608604
UR - http://link.springer.com/10.1023/A:1012582608604
TI - Positive hole transfer upon irradiation of frozen alkylbenzene solutions in freonic matrices at 77 K
T2 - High Energy Chemistry
AU - Egorov, A. V.
AU - Zezin, A A
AU - Feldman, V I
PY - 2001
DA - 2001/11/01
PB - Springer Nature
SP - 399-403
IS - 6
VL - 35
SN - 0018-1439
SN - 1608-3148
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2001_Egorov,
author = {A. V. Egorov and A A Zezin and V I Feldman},
title = {Positive hole transfer upon irradiation of frozen alkylbenzene solutions in freonic matrices at 77 K},
journal = {High Energy Chemistry},
year = {2001},
volume = {35},
publisher = {Springer Nature},
month = {nov},
url = {http://link.springer.com/10.1023/A:1012582608604},
number = {6},
pages = {399--403},
doi = {10.1023/A:1012582608604}
}
MLA
Cite this
MLA Copy
Egorov, A. V., et al. “Positive hole transfer upon irradiation of frozen alkylbenzene solutions in freonic matrices at 77 K.” High Energy Chemistry, vol. 35, no. 6, Nov. 2001, pp. 399-403. http://link.springer.com/10.1023/A:1012582608604.