Russian Chemical Bulletin

, том 50 , издание 7 , страницы 1295-1298

Bis-(2-diphenylphosphinoethyl)cyclopentadienylchlorolutetium: Synthesis and dynamic behavior in solution

M. D. ¹

Roitershtein ²

P. D. ²

Krutko ²

E. N. ³

Veksler ³

Скрыть аффилиации авторов Показать аффилиации авторов: 3 аффилиации

State Scientific Center of the Russian Federation “L. Ya. Karpov Institute of Physical Chemistry”, Moscow, Russian Federation |

Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie Gory, Moscow, Russian Federation |

Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai, People's Republic of China |

Тип публикации: Journal Article

Дата публикации: 2001-01-01

Springer Nature

Russian Chemical Bulletin

scimago Q3

БС2

SJR: 0.305

CiteScore: 2.8

Impact factor: —

ISSN: 10665285, 15739171

DOI: 10.1023/A:1014031512361

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General Chemistry

Краткое описание

The new biscyclopentadienyl lutetium complex (η5:η1-C5H4CH2CH2PPh2)2LuCl was synthesized by the reaction of LuCl3(THF)3 with lithium (2-diphenylphosphinoethyl)cyclopentadienide. Its behavior in solution was investigated by dynamic NMR spectroscopy. It was shown that the coordination of both phosphino groups to the lutetium center is retained over the whole temperature range studied. The barrier to pseudo-rotation for the trigonal bipyramid, which governs the intramolecular dynamics of this complex, was determined.

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Coordination Chemistry Reviews	Coordination Chemistry Reviews, 1, 50% Coordination Chemistry Reviews 1 публикация, 50%
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Elsevier	Elsevier, 2, 100% Elsevier 2 публикации, 100%
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D. M. et al. Bis-(2-diphenylphosphinoethyl)cyclopentadienylchlorolutetium: Synthesis and dynamic behavior in solution // Russian Chemical Bulletin. 2001. Vol. 50. No. 7. pp. 1295-1298.

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D. M., Roitershtein, D. P., Krutko, E. N., Veksler Bis-(2-diphenylphosphinoethyl)cyclopentadienylchlorolutetium: Synthesis and dynamic behavior in solution // Russian Chemical Bulletin. 2001. Vol. 50. No. 7. pp. 1295-1298.

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TY - JOUR

DO - 10.1023/A:1014031512361

UR - http://link.springer.com/10.1023/A:1014031512361

TI - Bis-(2-diphenylphosphinoethyl)cyclopentadienylchlorolutetium: Synthesis and dynamic behavior in solution

T2 - Russian Chemical Bulletin

AU - D., M.

AU - Roitershtein

AU - D., P.

AU - Krutko

AU - E. N.

AU - Veksler

PY - 2001

DA - 2001/01/01

PB - Springer Nature

SP - 1295-1298

IS - 7

VL - 50

SN - 1066-5285

SN - 1573-9171

ER -

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@article{2001_D.,

author = {M. D. and Roitershtein and P. D. and Krutko and E. N. and Veksler},

title = {Bis-(2-diphenylphosphinoethyl)cyclopentadienylchlorolutetium: Synthesis and dynamic behavior in solution},

journal = {Russian Chemical Bulletin},

year = {2001},

volume = {50},

publisher = {Springer Nature},

month = {jan},

url = {http://link.springer.com/10.1023/A:1014031512361},

number = {7},

pages = {1295--1298},

doi = {10.1023/A:1014031512361}

}

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D., M., et al. “Bis-(2-diphenylphosphinoethyl)cyclopentadienylchlorolutetium: Synthesis and dynamic behavior in solution.” Russian Chemical Bulletin, vol. 50, no. 7, Jan. 2001, pp. 1295-1298. http://link.springer.com/10.1023/A:1014031512361.