Springer Nature
Russian Chemical Bulletin
,  volume 50 ,  issue 7 ,  pages 1295-1298

Bis-(2-diphenylphosphinoethyl)cyclopentadienylchlorolutetium: Synthesis and dynamic behavior in solution

Publication type: Journal Article
Publication date: 2001-01-01
Springer Nature
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
The new biscyclopentadienyl lutetium complex (η5:η1-C5H4CH2CH2PPh2)2LuCl was synthesized by the reaction of LuCl3(THF)3 with lithium (2-diphenylphosphinoethyl)cyclopentadienide. Its behavior in solution was investigated by dynamic NMR spectroscopy. It was shown that the coordination of both phosphino groups to the lutetium center is retained over the whole temperature range studied. The barrier to pseudo-rotation for the trigonal bipyramid, which governs the intramolecular dynamics of this complex, was determined.
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D. M. et al. Bis-(2-diphenylphosphinoethyl)cyclopentadienylchlorolutetium: Synthesis and dynamic behavior in solution // Russian Chemical Bulletin. 2001. Vol. 50. No. 7. pp. 1295-1298.
GOST all authors (up to 50) Copy
D. M., Roitershtein, D. P., Krutko, E. N., Veksler Bis-(2-diphenylphosphinoethyl)cyclopentadienylchlorolutetium: Synthesis and dynamic behavior in solution // Russian Chemical Bulletin. 2001. Vol. 50. No. 7. pp. 1295-1298.
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RIS Copy
TY - JOUR
DO - 10.1023/A:1014031512361
UR - http://link.springer.com/10.1023/A:1014031512361
TI - Bis-(2-diphenylphosphinoethyl)cyclopentadienylchlorolutetium: Synthesis and dynamic behavior in solution
T2 - Russian Chemical Bulletin
AU - D., M.
AU - Roitershtein
AU - D., P.
AU - Krutko
AU - E. N.
AU - Veksler
PY - 2001
DA - 2001/01/01
PB - Springer Nature
SP - 1295-1298
IS - 7
VL - 50
SN - 1066-5285
SN - 1573-9171
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2001_D.,
author = {M. D. and Roitershtein and P. D. and Krutko and E. N. and Veksler},
title = {Bis-(2-diphenylphosphinoethyl)cyclopentadienylchlorolutetium: Synthesis and dynamic behavior in solution},
journal = {Russian Chemical Bulletin},
year = {2001},
volume = {50},
publisher = {Springer Nature},
month = {jan},
url = {http://link.springer.com/10.1023/A:1014031512361},
number = {7},
pages = {1295--1298},
doi = {10.1023/A:1014031512361}
}
MLA
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MLA Copy
D., M., et al. “Bis-(2-diphenylphosphinoethyl)cyclopentadienylchlorolutetium: Synthesis and dynamic behavior in solution.” Russian Chemical Bulletin, vol. 50, no. 7, Jan. 2001, pp. 1295-1298. http://link.springer.com/10.1023/A:1014031512361.