Intermediates of photolysis of 1,3,2,4-benzodithiadiazines studied by matrix isolation spectroscopy and quantum chemistry
N P Gritsan
1, 2
,
V A Bagryansky
1, 2
,
I V Vlasyuk
2
,
Yu N Molin
1, 2
,
A Yu Makarov
3
,
M.S. Platz
4
,
A V Zibarev
3
Publication type: Journal Article
Publication date: 2001-01-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
Photolysis of 12π-electron, formally antiaromatic, 1,3,2,4-benzodithiadiazine (1a) and its tetrafluoro-substituted derivative (1b) was studied in glassy matrices at 77 K and in an argon matrix at 14 K by UV, IR, and ESR spectroscopy. In these matrices, a diamagnetic species (3a,b) is formed as a persistent species. It is product of the intramolecular transformations of heterocycles 1a,b and the precursor of 1,2,3-benzodithiazolyl radicals (2a,b). The nitrenoid structure, intermediate between the structures of singlet 1,2,3-benzodithiazol-2-ylnitrene RS—N: and the corresponding thiazyl RS≡N, was ascribed to intermediate 3a,b in agreement with the data of IR spectroscopy.
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Total citations:
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Citations from 2024:
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(7.14%)
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Gritsan N. P. et al. Intermediates of photolysis of 1,3,2,4-benzodithiadiazines studied by matrix isolation spectroscopy and quantum chemistry // Russian Chemical Bulletin. 2001. Vol. 50. No. 11. pp. 2064-2070.
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Gritsan N. P., Bagryansky V. A., Vlasyuk I. V., Molin Yu. N., Makarov A. Yu., Platz M., Zibarev A. V. Intermediates of photolysis of 1,3,2,4-benzodithiadiazines studied by matrix isolation spectroscopy and quantum chemistry // Russian Chemical Bulletin. 2001. Vol. 50. No. 11. pp. 2064-2070.
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TY - JOUR
DO - 10.1023/A:1015032814197
UR - https://doi.org/10.1023/A:1015032814197
TI - Intermediates of photolysis of 1,3,2,4-benzodithiadiazines studied by matrix isolation spectroscopy and quantum chemistry
T2 - Russian Chemical Bulletin
AU - Gritsan, N P
AU - Bagryansky, V A
AU - Vlasyuk, I V
AU - Molin, Yu N
AU - Makarov, A Yu
AU - Platz, M.S.
AU - Zibarev, A V
PY - 2001
DA - 2001/01/01
PB - Springer Nature
SP - 2064-2070
IS - 11
VL - 50
SN - 1066-5285
SN - 1573-9171
ER -
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@article{2001_Gritsan,
author = {N P Gritsan and V A Bagryansky and I V Vlasyuk and Yu N Molin and A Yu Makarov and M.S. Platz and A V Zibarev},
title = {Intermediates of photolysis of 1,3,2,4-benzodithiadiazines studied by matrix isolation spectroscopy and quantum chemistry},
journal = {Russian Chemical Bulletin},
year = {2001},
volume = {50},
publisher = {Springer Nature},
month = {jan},
url = {https://doi.org/10.1023/A:1015032814197},
number = {11},
pages = {2064--2070},
doi = {10.1023/A:1015032814197}
}
Cite this
MLA
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Gritsan, N. P., et al. “Intermediates of photolysis of 1,3,2,4-benzodithiadiazines studied by matrix isolation spectroscopy and quantum chemistry.” Russian Chemical Bulletin, vol. 50, no. 11, Jan. 2001, pp. 2064-2070. https://doi.org/10.1023/A:1015032814197.