Formation of coordination polymeric structures on the basis of 4,4′-dipyridylethylene and Ag+ in solutions
Publication type: Journal Article
Publication date: 2002-12-28
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
A new inorganic supramolecular complex [Hg6As4](InCl6)Cl was synthesized. The complex crystallizes in the cubic space group Pa3 with the unit cell parameter a = 12.109(1) Å and Z = 4. The crystal structure of the complex is based on the ∞ 3[Hg6As4]4+ three-dimensional cationic host framework. The guest InCl6 3– and Cl– anions are located in the cavities of the framework. The host—guest interactions were examined by quantum-chemical calculations of the equilibrium geometry of the InCl6 3– anion and analysis of the periodic zero-potential surface of the supramolecular complex. It was demonstrated that the electrostatic factors dominate over the covalent factors in the organization of the supramolecular structure of [Hg6As4](InCl6)Cl.
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Olenev A. et al. Formation of coordination polymeric structures on the basis of 4,4′-dipyridylethylene and Ag+ in solutions // Russian Chemical Bulletin. 2002. Vol. 51. No. 3. pp. 444-448.
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Olenev A., Baranov A. I., Shatruk M. M., Tyablikov A. S., Shevelkov A. V. Formation of coordination polymeric structures on the basis of 4,4′-dipyridylethylene and Ag+ in solutions // Russian Chemical Bulletin. 2002. Vol. 51. No. 3. pp. 444-448.
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TY - JOUR
DO - 10.1023/A:1015500116907
UR - http://link.springer.com/10.1023/A:1015500116907
TI - Formation of coordination polymeric structures on the basis of 4,4′-dipyridylethylene and Ag+ in solutions
T2 - Russian Chemical Bulletin
AU - Olenev, A.V.
AU - Baranov, A. I.
AU - Shatruk, M M
AU - Tyablikov, A S
AU - Shevelkov, A. V.
PY - 2002
DA - 2002/12/28
PB - Springer Nature
SP - 444-448
IS - 3
VL - 51
SN - 1066-5285
SN - 1573-9171
ER -
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BibTex (up to 50 authors)
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@article{2002_Olenev,
author = {A.V. Olenev and A. I. Baranov and M M Shatruk and A S Tyablikov and A. V. Shevelkov},
title = {Formation of coordination polymeric structures on the basis of 4,4′-dipyridylethylene and Ag+ in solutions},
journal = {Russian Chemical Bulletin},
year = {2002},
volume = {51},
publisher = {Springer Nature},
month = {dec},
url = {http://link.springer.com/10.1023/A:1015500116907},
number = {3},
pages = {444--448},
doi = {10.1023/A:1015500116907}
}
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MLA
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Olenev, A.V., et al. “Formation of coordination polymeric structures on the basis of 4,4′-dipyridylethylene and Ag+ in solutions.” Russian Chemical Bulletin, vol. 51, no. 3, Dec. 2002, pp. 444-448. http://link.springer.com/10.1023/A:1015500116907.