Interaction between a Decahydro-closo-Decaborate(2–) Anion and Aliphatic Carboxylic Acids

K Yu Zhizhin 1
O O Vovk 1
E. A. Malinina 1
V N Mustyatsa 1
L. V. Goeva 1
I N Polyakova 1
N. T. Kuznetsov 1
Publication typeJournal Article
Publication date2001-01-01
scimago Q4
wos Q4
SJR0.189
CiteScore1.7
Impact factor1.1
ISSN10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
Interaction between a closo-decaborate anion B10H2– 10and carboxylic acids RCOOH (R = H, CH3, C2H5, iso-C3H7, C4H9) is studied. The mono-, di- tri- and tetrasubstituted products B10H10 – n (OCOR)2– n are formed in sequence with the temperature growth. The reaction follows an essentially regioselective mechanism: only one of all possible isomers forms at every stage of the process. The respective hydroxy-closo-decaborates B10H10 – n (OH)2– n were prepared by alkaline hydrolysis in aqueous and nonaqueous solutions. All the compounds were identified by chemical analysis and 11B NMR and IR spectroscopy. The crystal structure of [Pb(Bipy)(DMF)(B10H9OH)] · DMF was determined by X-ray diffraction.
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Zhizhin K. Yu. et al. Interaction between a Decahydro-closo-Decaborate(2–) Anion and Aliphatic Carboxylic Acids // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2001. Vol. 27. No. 9. pp. 613-619.
GOST all authors (up to 50) Copy
Zhizhin K. Yu., Vovk O. O., Malinina E. A., Mustyatsa V. N., Goeva L. V., Polyakova I. N., Kuznetsov N. T. Interaction between a Decahydro-closo-Decaborate(2–) Anion and Aliphatic Carboxylic Acids // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2001. Vol. 27. No. 9. pp. 613-619.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1023/A:1017937102647
UR - https://doi.org/10.1023/A:1017937102647
TI - Interaction between a Decahydro-closo-Decaborate(2–) Anion and Aliphatic Carboxylic Acids
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Zhizhin, K Yu
AU - Vovk, O O
AU - Malinina, E. A.
AU - Mustyatsa, V N
AU - Goeva, L. V.
AU - Polyakova, I N
AU - Kuznetsov, N. T.
PY - 2001
DA - 2001/01/01
PB - Pleiades Publishing
SP - 613-619
IS - 9
VL - 27
SN - 1070-3284
SN - 1608-3318
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2001_Zhizhin,
author = {K Yu Zhizhin and O O Vovk and E. A. Malinina and V N Mustyatsa and L. V. Goeva and I N Polyakova and N. T. Kuznetsov},
title = {Interaction between a Decahydro-closo-Decaborate(2–) Anion and Aliphatic Carboxylic Acids},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2001},
volume = {27},
publisher = {Pleiades Publishing},
month = {jan},
url = {https://doi.org/10.1023/A:1017937102647},
number = {9},
pages = {613--619},
doi = {10.1023/A:1017937102647}
}
MLA
Cite this
MLA Copy
Zhizhin, K. Yu., et al. “Interaction between a Decahydro-closo-Decaborate(2–) Anion and Aliphatic Carboxylic Acids.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 27, no. 9, Jan. 2001, pp. 613-619. https://doi.org/10.1023/A:1017937102647.