,
volume 27
,
issue 9
,
pages 619-621
The Mechanism of Acid-Catalyzed Nucleophilic Substitution in Decahydro-closo-Decaborate(2–) Anions
Publication type: Journal Article
Publication date: 2001-01-01
scimago Q4
wos Q4
SJR: 0.189
CiteScore: 1.7
Impact factor: 1.1
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
The reactions of salts formed by the B10H2– 10anion with carboxylic acids were studied. From the model systems Cat2B10H10+ HCOOH (Cat = Et4N+, Bu4N+, Ph4P+, Ph4As+), several intermediates were isolated and characterized. A mechanism was proposed for the replacement of the exo-polyhedral hydrogen atoms in B10H2– 10by carboxylate groups in the reactions of Cat2B10H10with carboxylic acids.
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GOST
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Zhizhin K. Yu. et al. The Mechanism of Acid-Catalyzed Nucleophilic Substitution in Decahydro-closo-Decaborate(2–) Anions // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2001. Vol. 27. No. 9. pp. 619-621.
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Zhizhin K. Yu., Mustyatsa V. N., Malinina E. A., Goeva L. V., Kuznetsov N. T. The Mechanism of Acid-Catalyzed Nucleophilic Substitution in Decahydro-closo-Decaborate(2–) Anions // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2001. Vol. 27. No. 9. pp. 619-621.
Cite this
RIS
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TY - JOUR
DO - 10.1023/A:1017989219486
UR - https://doi.org/10.1023/A:1017989219486
TI - The Mechanism of Acid-Catalyzed Nucleophilic Substitution in Decahydro-closo-Decaborate(2–) Anions
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Zhizhin, K Yu
AU - Mustyatsa, V N
AU - Malinina, E. A.
AU - Goeva, L. V.
AU - Kuznetsov, N. T.
PY - 2001
DA - 2001/01/01
PB - Pleiades Publishing
SP - 619-621
IS - 9
VL - 27
SN - 1070-3284
SN - 1608-3318
ER -
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BibTex (up to 50 authors)
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@article{2001_Zhizhin,
author = {K Yu Zhizhin and V N Mustyatsa and E. A. Malinina and L. V. Goeva and N. T. Kuznetsov},
title = {The Mechanism of Acid-Catalyzed Nucleophilic Substitution in Decahydro-closo-Decaborate(2–) Anions},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2001},
volume = {27},
publisher = {Pleiades Publishing},
month = {jan},
url = {https://doi.org/10.1023/A:1017989219486},
number = {9},
pages = {619--621},
doi = {10.1023/A:1017989219486}
}
Cite this
MLA
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Zhizhin, K. Yu., et al. “The Mechanism of Acid-Catalyzed Nucleophilic Substitution in Decahydro-closo-Decaborate(2–) Anions.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 27, no. 9, Jan. 2001, pp. 619-621. https://doi.org/10.1023/A:1017989219486.
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