High Energy Chemistry

, volume 36 , issue 5 , pages 309-315

Spectral characteristics and transformations of intermediates in irradiated Freon 11, Freon 113, and Freon 113a

M Ya Melnikov ¹

D V Baskakov ¹

V I Feldman ²

Hide authors affiliations Show authors affiliations: 2 affiliations

Moscow State University, Moscow, Russia |

Karpov institute of physical chemistry, Moscow, Russia |

Publication type: Journal Article

Publication date: 2002-01-01

Springer Nature

High Energy Chemistry

scimago Q4

wos Q4

SJR: 0.178

CiteScore: 0.9

Impact factor: 0.6

ISSN: 00181439, 16083148

DOI: 10.1023/A:1020290432120

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Physical and Theoretical Chemistry

Abstract

Optical absorption bands observable in Freon 11, Freon 113, and Freon 113a irradiated at 77 K were assigned to various intermediates (radical cations, radical ion pairs, and complexes of radicals with ions). The transformations of these species in thermal and photochemical reactions occurring at 77 K were studied. On the basis of experimental results, it was suggested that the radical anions of Freon 11 and Freon 113 are unstable at 77 K and the spatial distribution of the intermediates produced is inhomogeneous.

Found

1 citation

Tyurin Daniil

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PhD in Chemistry

72 publications, 683 citations

h-index: 15

Lomonosov Moscow State University

Computational chemistry

Computational methods in chemistry

Cryogenic technology

EPR spectroscopy

High-performance computing

IR spectroscopy

Interaction of X-ray and synchrotron radiation with matter

Matrix isolation

Molecular modeling

Molecular spectroscopy

Non-covalent Interactions

Non-valent interactions

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Savostina Liudmila

PhD in Physics and Mathematics

14 publications, 52 citations, 1 review

h-index: 4

Kazan Federal University

Kazan E.K. Zavoisky Physical-Technical Institute of the Kazan Scientific Center of the Russian Academy of Sciences

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Melnikov M. Ya. et al. Spectral characteristics and transformations of intermediates in irradiated Freon 11, Freon 113, and Freon 113a // High Energy Chemistry. 2002. Vol. 36. No. 5. pp. 309-315.

GOST all authors (up to 50) Copy

Melnikov M. Ya., Baskakov D. V., Feldman V. I. Spectral characteristics and transformations of intermediates in irradiated Freon 11, Freon 113, and Freon 113a // High Energy Chemistry. 2002. Vol. 36. No. 5. pp. 309-315.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1023/A:1020290432120

UR - http://link.springer.com/10.1023/A:1020290432120

TI - Spectral characteristics and transformations of intermediates in irradiated Freon 11, Freon 113, and Freon 113a

T2 - High Energy Chemistry

AU - Melnikov, M Ya

AU - Baskakov, D V

AU - Feldman, V I

PY - 2002

DA - 2002/01/01

PB - Springer Nature

SP - 309-315

IS - 5

VL - 36

SN - 0018-1439

SN - 1608-3148

ER -

BibTex |

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BibTex (up to 50 authors) Copy

@article{2002_Melnikov,

author = {M Ya Melnikov and D V Baskakov and V I Feldman},

title = {Spectral characteristics and transformations of intermediates in irradiated Freon 11, Freon 113, and Freon 113a},

journal = {High Energy Chemistry},

year = {2002},

volume = {36},

publisher = {Springer Nature},

month = {jan},

url = {http://link.springer.com/10.1023/A:1020290432120},

number = {5},

pages = {309--315},

doi = {10.1023/A:1020290432120}

}

MLA

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MLA Copy

Melnikov, M. Ya., et al. “Spectral characteristics and transformations of intermediates in irradiated Freon 11, Freon 113, and Freon 113a.” High Energy Chemistry, vol. 36, no. 5, Jan. 2002, pp. 309-315. http://link.springer.com/10.1023/A:1020290432120.