Springer Nature
High Energy Chemistry
,  том 37 ,  издание 2 ,  страницы 96-100

Photochemistry of Ethylbenzene Radical Cations in Low-Temperature Freonic Matrices

Тип публикации: Journal Article
Дата публикации: 2003-03-01
Springer Nature
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SJR: 0.178
CiteScore: 0.9
Impact factor: 0.6
ISSN: 00181439, 16083148
Physical and Theoretical Chemistry
Краткое описание
Two different conformers of ethylbenzene radical cations (or a mixture of both conformers) can be stabilized in various freonic matrices. The first conformer retains the geometry of the parent molecule, whereas the second one corresponds to minimum energy. It was shown that the photochemical reactions of the radical cations in various freons at 77 K were not accompanied by a change in their conformational state. The spectral characteristics of ethylbenzene radical cations and the quantum yields of photoinduced charge transfer reactions were determined. The reasons for stabilization of different conformers of the radical cations in different freonic matrices are discussed.
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Melnikov M. Ya. et al. Photochemistry of Ethylbenzene Radical Cations in Low-Temperature Freonic Matrices // High Energy Chemistry. 2003. Vol. 37. No. 2. pp. 96-100.
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Melnikov M. Ya., Marushkevich K. I., Baranova I. A., Melnikova O. L., Tyurin D. A. Photochemistry of Ethylbenzene Radical Cations in Low-Temperature Freonic Matrices // High Energy Chemistry. 2003. Vol. 37. No. 2. pp. 96-100.
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TY - JOUR
DO - 10.1023/A:1022836415986
UR - http://link.springer.com/10.1023/A:1022836415986
TI - Photochemistry of Ethylbenzene Radical Cations in Low-Temperature Freonic Matrices
T2 - High Energy Chemistry
AU - Melnikov, M Ya
AU - Marushkevich, K I
AU - Baranova, I A
AU - Melnikova, O L
AU - Tyurin, D A
PY - 2003
DA - 2003/03/01
PB - Springer Nature
SP - 96-100
IS - 2
VL - 37
SN - 0018-1439
SN - 1608-3148
ER -
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@article{2003_Melnikov,
author = {M Ya Melnikov and K I Marushkevich and I A Baranova and O L Melnikova and D A Tyurin},
title = {Photochemistry of Ethylbenzene Radical Cations in Low-Temperature Freonic Matrices},
journal = {High Energy Chemistry},
year = {2003},
volume = {37},
publisher = {Springer Nature},
month = {mar},
url = {http://link.springer.com/10.1023/A:1022836415986},
number = {2},
pages = {96--100},
doi = {10.1023/A:1022836415986}
}
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Melnikov, M. Ya., et al. “Photochemistry of Ethylbenzene Radical Cations in Low-Temperature Freonic Matrices.” High Energy Chemistry, vol. 37, no. 2, Mar. 2003, pp. 96-100. http://link.springer.com/10.1023/A:1022836415986.