The synthesis and structural characterisation of [IrCl(COD)(PEt3) n ], n = 1 or 2, and orthometallated Vaska's compound, [IrHCl(CO)(PPh3)η 2-PPh2(C6H4)]
Тип публикации: Journal Article
Дата публикации: 2003-09-16
scimago Q3
wos Q3
БС3
SJR: 0.24
CiteScore: 3
Impact factor: 1.7
ISSN: 03404285, 1572901X
Materials Chemistry
Metals and Alloys
Inorganic Chemistry
Краткое описание
Two iridium(I) complexes, [IrCl(COD)(PEt3) n ], n = 1 or 2, have been prepared and structurally characterised. Although [IrCl(COD)(PEt3)] is a known compound the spectroscopic data on both compounds is presented and discussed. In addition, the X-ray crystal structure of the previously described orthometallated isomer of Vaska's compound, [IrHCl(CO)(PPh3)η 2-PPh2(C6H4)], is reported to show the hydride ligand trans- to the carbonyl ligand.
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Brym M., Jones C. The synthesis and structural characterisation of [IrCl(COD)(PEt3) n ], n = 1 or 2, and orthometallated Vaska's compound, [IrHCl(CO)(PPh3)η 2-PPh2(C6H4)] // Transition Metal Chemistry. 2003. Vol. 28. No. 5. pp. 595-599.
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Brym M., Jones C. The synthesis and structural characterisation of [IrCl(COD)(PEt3) n ], n = 1 or 2, and orthometallated Vaska's compound, [IrHCl(CO)(PPh3)η 2-PPh2(C6H4)] // Transition Metal Chemistry. 2003. Vol. 28. No. 5. pp. 595-599.
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TY - JOUR
DO - 10.1023/a:1025044229274
UR - https://doi.org/10.1023/a:1025044229274
TI - The synthesis and structural characterisation of [IrCl(COD)(PEt3) n ], n = 1 or 2, and orthometallated Vaska's compound, [IrHCl(CO)(PPh3)η 2-PPh2(C6H4)]
T2 - Transition Metal Chemistry
AU - Brym, Markus
AU - Jones, Cameron
PY - 2003
DA - 2003/09/16
PB - Springer Nature
SP - 595-599
IS - 5
VL - 28
SN - 0340-4285
SN - 1572-901X
ER -
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@article{2003_Brym,
author = {Markus Brym and Cameron Jones},
title = {The synthesis and structural characterisation of [IrCl(COD)(PEt3) n ], n = 1 or 2, and orthometallated Vaska's compound, [IrHCl(CO)(PPh3)η 2-PPh2(C6H4)]},
journal = {Transition Metal Chemistry},
year = {2003},
volume = {28},
publisher = {Springer Nature},
month = {sep},
url = {https://doi.org/10.1023/a:1025044229274},
number = {5},
pages = {595--599},
doi = {10.1023/a:1025044229274}
}
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Brym, Markus, and Cameron Jones. “The synthesis and structural characterisation of [IrCl(COD)(PEt3) n ], n = 1 or 2, and orthometallated Vaska's compound, [IrHCl(CO)(PPh3)η 2-PPh2(C6H4)].” Transition Metal Chemistry, vol. 28, no. 5, Sep. 2003, pp. 595-599. https://doi.org/10.1023/a:1025044229274.