Reaction of Some Dibromomethyl-Substituted Cyclohexadienones with Molecular Bromine
Publication type: Journal Article
Publication date: 2003-09-23
scimago Q4
wos Q4
SJR: 0.190
CiteScore: 1.3
Impact factor: 0.9
ISSN: 10704280, 16083393
Organic Chemistry
Abstract
Abstract4-Dibromomethyl-4-methyl-2,5-cyclohexadienone and its 2- and 3-methyl-substituted derivatives react with an equimolar amount of molecular bromine in carbon tetrachloride, yielding vinyl bromination products at the α-position with respect to the carbonyl group. The reaction of 4-dibromomethyl-3,4-dimethyl-2,5-cyclohexadienone with a large excess of bromine, apart from the vinyl bromination product, gives the corresponding 3-bromomethyl and 3-dibromomethyl derivatives. 4-Dibromomethyl-2,4-dimethyl-2,5-cyclohexadienone takes up bromine molecule at the C2ÍC3 double bond.
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Gavrilova G. V. et al. Reaction of Some Dibromomethyl-Substituted Cyclohexadienones with Molecular Bromine // Russian Journal of Organic Chemistry. 2003. Vol. 39. No. 3. pp. 361-367.
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Gavrilova G. V., Gavrilov A., Krutko D. P., Butin K. Reaction of Some Dibromomethyl-Substituted Cyclohexadienones with Molecular Bromine // Russian Journal of Organic Chemistry. 2003. Vol. 39. No. 3. pp. 361-367.
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TY - JOUR
DO - 10.1023/A:1025589614195
UR - https://doi.org/10.1023/A:1025589614195
TI - Reaction of Some Dibromomethyl-Substituted Cyclohexadienones with Molecular Bromine
T2 - Russian Journal of Organic Chemistry
AU - Gavrilova, G V
AU - Gavrilov, A.A.
AU - Krutko, D P
AU - Butin, K.P.
PY - 2003
DA - 2003/09/23
PB - Pleiades Publishing
SP - 361-367
IS - 3
VL - 39
SN - 1070-4280
SN - 1608-3393
ER -
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BibTex (up to 50 authors)
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@article{2003_Gavrilova,
author = {G V Gavrilova and A.A. Gavrilov and D P Krutko and K.P. Butin},
title = {Reaction of Some Dibromomethyl-Substituted Cyclohexadienones with Molecular Bromine},
journal = {Russian Journal of Organic Chemistry},
year = {2003},
volume = {39},
publisher = {Pleiades Publishing},
month = {sep},
url = {https://doi.org/10.1023/A:1025589614195},
number = {3},
pages = {361--367},
doi = {10.1023/A:1025589614195}
}
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Gavrilova, G. V., et al. “Reaction of Some Dibromomethyl-Substituted Cyclohexadienones with Molecular Bromine.” Russian Journal of Organic Chemistry, vol. 39, no. 3, Sep. 2003, pp. 361-367. https://doi.org/10.1023/A:1025589614195.
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