,
volume 26
,
issue 12
,
pages 866-871
Synthesis and IR spectral study of MoO2 Cl2 molecular complexes with acetoacetanilides. Crystal structure of MoO2 Cl2 complex with acetoacet-2-toluidine
1
East Ukrainian State University, Lugansk, Ukraine
|
Publication type: Journal Article
Publication date: 2000-01-01
scimago Q4
wos Q4
SJR: 0.189
CiteScore: 1.7
Impact factor: 1.1
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
A series of MoO2Cl2 complexes with acetoacetanilide derivatives were synthesized and studied by IR spectroscopy. The crystal and molecular structures of the MoO2Cl2 complex with acetoacet-2-toluidine (HL) were determined by X-ray diffraction analysis. The monoclinic crystals involved are a = 7.621(7) Å, b = 9.498(3) Å, c = 19.980(9) Å, β = 95.16(7)°, V = 1440(2) Å3, Z = 4, and space group P21/n. The coordination polyhedron of the Mo atom is a distorted octahedron with two O oxoatoms in the cis-position relative to each other, two Cl atoms in the trans-positions, and two O atoms (HL) in the trans-positions to O(oxo).
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Abramenko V. L. Synthesis and IR spectral study of MoO2Cl2 molecular complexes with acetoacetanilides. Crystal structure of MoO2Cl2 complex with acetoacet-2-toluidine // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2000. Vol. 26. No. 12. pp. 866-871.
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Abramenko V. L. Synthesis and IR spectral study of MoO2Cl2 molecular complexes with acetoacetanilides. Crystal structure of MoO2Cl2 complex with acetoacet-2-toluidine // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2000. Vol. 26. No. 12. pp. 866-871.
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TY - JOUR
DO - 10.1023/A:1026679009037
UR - http://link.springer.com/10.1023/A:1026679009037
TI - Synthesis and IR spectral study of MoO2Cl2 molecular complexes with acetoacetanilides. Crystal structure of MoO2Cl2 complex with acetoacet-2-toluidine
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Abramenko, V L
PY - 2000
DA - 2000/01/01
PB - Springer Nature
SP - 866-871
IS - 12
VL - 26
SN - 1070-3284
SN - 1608-3318
ER -
Cite this
BibTex (up to 50 authors)
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@article{2000_Abramenko,
author = {V L Abramenko},
title = {Synthesis and IR spectral study of MoO2Cl2 molecular complexes with acetoacetanilides. Crystal structure of MoO2Cl2 complex with acetoacet-2-toluidine},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2000},
volume = {26},
publisher = {Springer Nature},
month = {jan},
url = {http://link.springer.com/10.1023/A:1026679009037},
number = {12},
pages = {866--871},
doi = {10.1023/A:1026679009037}
}
Cite this
MLA
Copy
Abramenko, V. L., et al. “Synthesis and IR spectral study of MoO2Cl2 molecular complexes with acetoacetanilides. Crystal structure of MoO2Cl2 complex with acetoacet-2-toluidine.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 26, no. 12, Jan. 2000, pp. 866-871. http://link.springer.com/10.1023/A:1026679009037.