volume 40 issue 9 pages 967-970

Synthesis of NASICON-Type Lithium Zirconium Phosphate

Publication typeJournal Article
Publication date2004-09-15
scimago Q4
wos Q4
SJR0.183
CiteScore1.3
Impact factor0.7
ISSN00201685, 16083172
Materials Chemistry
Metals and Alloys
Inorganic Chemistry
General Chemical Engineering
Abstract
The chemical transformations involved in the synthesis of the NASICON-type compound LiZr2(PO4)3 were studied by thermogravimetry and x-ray diffraction. The results demonstrate that, during heat treatment of a 3Zr(HPO4)2 · 2H2O + Li2CO3 + ZrO2 mixture, the formation of the NASICON phase begins at 600°C. Further heating, however, leads to the concurrent formation of zirconium diphosphate and uncontrolled lithium losses because of the high volatility of Li compounds. A well-crystallized, high-conductivity NASICON phase is formed only above 1100°C. Phase-pure LiZr2(PO4)3 can only obtained by a two-step procedure.
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GOST |
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GOST Copy
Stenina I. A. et al. Synthesis of NASICON-Type Lithium Zirconium Phosphate // Inorganic Materials. 2004. Vol. 40. No. 9. pp. 967-970.
GOST all authors (up to 50) Copy
Stenina I. A., Velikodnyi Y., Ketsko V. A., Yaroslavtsev A. B. Synthesis of NASICON-Type Lithium Zirconium Phosphate // Inorganic Materials. 2004. Vol. 40. No. 9. pp. 967-970.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1023/B:INMA.0000041330.84296.2e
UR - http://link.springer.com/10.1023/B:INMA.0000041330.84296.2e
TI - Synthesis of NASICON-Type Lithium Zirconium Phosphate
T2 - Inorganic Materials
AU - Stenina, I A
AU - Velikodnyi, Yu.A.
AU - Ketsko, V A
AU - Yaroslavtsev, A. B.
PY - 2004
DA - 2004/09/15
PB - Springer Nature
SP - 967-970
IS - 9
VL - 40
SN - 0020-1685
SN - 1608-3172
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2004_Stenina,
author = {I A Stenina and Yu.A. Velikodnyi and V A Ketsko and A. B. Yaroslavtsev},
title = {Synthesis of NASICON-Type Lithium Zirconium Phosphate},
journal = {Inorganic Materials},
year = {2004},
volume = {40},
publisher = {Springer Nature},
month = {sep},
url = {http://link.springer.com/10.1023/B:INMA.0000041330.84296.2e},
number = {9},
pages = {967--970},
doi = {10.1023/B:INMA.0000041330.84296.2e}
}
MLA
Cite this
MLA Copy
Stenina, I. A., et al. “Synthesis of NASICON-Type Lithium Zirconium Phosphate.” Inorganic Materials, vol. 40, no. 9, Sep. 2004, pp. 967-970. http://link.springer.com/10.1023/B:INMA.0000041330.84296.2e.