New palladium nanoclusters. Synthesis, structure, and catalytic properties
I P Stolyarov
1
,
Yu V Gaugash
1
,
G. N. Kryukova
2
,
D.I. Kochubei
2
,
M.N. Vargaftik
1
,
I. I. Moiseev
1
Publication type: Journal Article
Publication date: 2004-06-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
The reduction of palladium(ii) carboxylates Pd3(OCOR)6 (R = Me, Et, CHMe2, CMe3) with hydrogen in alcohol solutions containing 1,10-phenanthroline (phen) and subsequent oxidation with oxygen gave new palladium nanoclusters, mainly particles with a nearly spherical metal core and an average size of 18 Å. Based on elemental analysis, NMR, X-ray photoelectron spectroscopy, and EXAFS, nanoclusters were described by the idealized formula Pd147phen32O60(OCOR)30. The specimens contained up to ∼25% smaller 55-atomic Pd clusters with a ∼10 Å metal core. New nanoclusters catalyze hydrogenation of alkynes and alkenes, reduction of nitriles with formic acid, oxidation of aliphatic and benzylic alcohols, oxidative esterification of ethylene and propylene, and disproportionation of benzyl alcohol into toluene and benzaldehyde.
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Stolyarov I. P. et al. New palladium nanoclusters. Synthesis, structure, and catalytic properties // Russian Chemical Bulletin. 2004. Vol. 53. No. 6. pp. 1194-1199.
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Stolyarov I. P., Gaugash Yu. V., Kryukova G. N., Kochubei D., Vargaftik M., Moiseev I. I. New palladium nanoclusters. Synthesis, structure, and catalytic properties // Russian Chemical Bulletin. 2004. Vol. 53. No. 6. pp. 1194-1199.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1023/B:RUCB.0000042273.76439.7b
UR - http://link.springer.com/10.1023/B:RUCB.0000042273.76439.7b
TI - New palladium nanoclusters. Synthesis, structure, and catalytic properties
T2 - Russian Chemical Bulletin
AU - Stolyarov, I P
AU - Gaugash, Yu V
AU - Kryukova, G. N.
AU - Kochubei, D.I.
AU - Vargaftik, M.N.
AU - Moiseev, I. I.
PY - 2004
DA - 2004/06/01
PB - Springer Nature
SP - 1194-1199
IS - 6
VL - 53
SN - 1066-5285
SN - 1573-9171
ER -
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BibTex (up to 50 authors)
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@article{2004_Stolyarov,
author = {I P Stolyarov and Yu V Gaugash and G. N. Kryukova and D.I. Kochubei and M.N. Vargaftik and I. I. Moiseev},
title = {New palladium nanoclusters. Synthesis, structure, and catalytic properties},
journal = {Russian Chemical Bulletin},
year = {2004},
volume = {53},
publisher = {Springer Nature},
month = {jun},
url = {http://link.springer.com/10.1023/B:RUCB.0000042273.76439.7b},
number = {6},
pages = {1194--1199},
doi = {10.1023/B:RUCB.0000042273.76439.7b}
}
Cite this
MLA
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Stolyarov, I. P., et al. “New palladium nanoclusters. Synthesis, structure, and catalytic properties.” Russian Chemical Bulletin, vol. 53, no. 6, Jun. 2004, pp. 1194-1199. http://link.springer.com/10.1023/B:RUCB.0000042273.76439.7b.
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