Electrochemical Properties of Poly-o-Phenylenediamine Films in Solutions with Variable Concentration of Hydronium Ions
Publication type: Journal Article
Publication date: 2004-01-14
scimago Q4
wos Q4
SJR: 0.236
CiteScore: 1.9
Impact factor: 0.8
ISSN: 10231935, 16083342
Electrochemistry
Abstract
Electrochemical behavior of poly-o-phenylenediamine (PoPhD) films in lithium perchlorate and perchloric acid solutions of different pH and constant ionic strength is studied using cyclic voltammetry, low-amplitude chronoamperometry, chronopotentiometry, and faradaic-impedance spectroscopy. The experimental results point to the diffusion–migration kinetics of charge transfer processes in redox-active PoPhD films and show that two such processes occur during oxidation–reduction of PoPhD. The processes are separated most fully at low concentrations of hydronium ions. Effect of the electrode potential and electrolyte composition on these processes is examined. Different methods yield similar results and permit their more reliable interpretation.
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Levin O. V., Kondratev V. V., Malev V. V. Electrochemical Properties of Poly-o-Phenylenediamine Films in Solutions with Variable Concentration of Hydronium Ions // Russian Journal of Electrochemistry. 2004. Vol. 40. No. 1. pp. 91-98.
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Levin O. V., Kondratev V. V., Malev V. V. Electrochemical Properties of Poly-o-Phenylenediamine Films in Solutions with Variable Concentration of Hydronium Ions // Russian Journal of Electrochemistry. 2004. Vol. 40. No. 1. pp. 91-98.
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TY - JOUR
DO - 10.1023/B:RUEL.0000012080.14878.ad
UR - https://doi.org/10.1023/B:RUEL.0000012080.14878.ad
TI - Electrochemical Properties of Poly-o-Phenylenediamine Films in Solutions with Variable Concentration of Hydronium Ions
T2 - Russian Journal of Electrochemistry
AU - Levin, O. V.
AU - Kondratev, V V
AU - Malev, V V
PY - 2004
DA - 2004/01/14
PB - Pleiades Publishing
SP - 91-98
IS - 1
VL - 40
SN - 1023-1935
SN - 1608-3342
ER -
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BibTex (up to 50 authors)
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@article{2004_Levin,
author = {O. V. Levin and V V Kondratev and V V Malev},
title = {Electrochemical Properties of Poly-o-Phenylenediamine Films in Solutions with Variable Concentration of Hydronium Ions},
journal = {Russian Journal of Electrochemistry},
year = {2004},
volume = {40},
publisher = {Pleiades Publishing},
month = {jan},
url = {https://doi.org/10.1023/B:RUEL.0000012080.14878.ad},
number = {1},
pages = {91--98},
doi = {10.1023/B:RUEL.0000012080.14878.ad}
}
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MLA
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Levin, O. V., et al. “Electrochemical Properties of Poly-o-Phenylenediamine Films in Solutions with Variable Concentration of Hydronium Ions.” Russian Journal of Electrochemistry, vol. 40, no. 1, Jan. 2004, pp. 91-98. https://doi.org/10.1023/B:RUEL.0000012080.14878.ad.