Mathematical Modeling of the Plasma-Chemical Pyrolysis of Methane
Publication type: Journal Article
Publication date: 2002-12-23
scimago Q4
wos Q4
SJR: 0.178
CiteScore: 0.9
Impact factor: 0.6
ISSN: 00181439, 16083148
Physical and Theoretical Chemistry
Abstract
A mathematical model was developed for the plasma-chemical pyrolysis of methane, which includes the latest data on the mechanism and kinetics of chemical processes of hydrocarbon pyrolysis and mixing of methane jets with hydrogen heated in an arc plasma torch. The results of calculations on methane conversion and the synthesis of acetylene and its homologues satisfactorily agree with experimental data over a wide range of parameters of the process. It was shown that the methane conversion is initiated via interaction with atomic hydrogen, acetylene is produced through the dissociation of intermediate products involving radicals, and the consumption of acetylene is due to the synthesis of its homologues involving vinylidenecarbene and methylenecarbene in the ground and excited states.
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Metrics
23
Total citations:
23
Citations from 2025:
2
(9.1%)
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MLA
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GOST
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Slovetskii D. I. et al. Mathematical Modeling of the Plasma-Chemical Pyrolysis of Methane // High Energy Chemistry. 2002. Vol. 36. No. 1. pp. 44-52.
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Slovetskii D. I., Mankelevich Y., Slovetskii S. D., Rakhimova T. V. Mathematical Modeling of the Plasma-Chemical Pyrolysis of Methane // High Energy Chemistry. 2002. Vol. 36. No. 1. pp. 44-52.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1023/a:1013600628538
UR - https://doi.org/10.1023/a:1013600628538
TI - Mathematical Modeling of the Plasma-Chemical Pyrolysis of Methane
T2 - High Energy Chemistry
AU - Slovetskii, D I
AU - Mankelevich, Yu.A.
AU - Slovetskii, S D
AU - Rakhimova, T. V.
PY - 2002
DA - 2002/12/23
PB - Pleiades Publishing
SP - 44-52
IS - 1
VL - 36
SN - 0018-1439
SN - 1608-3148
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2002_Slovetskii,
author = {D I Slovetskii and Yu.A. Mankelevich and S D Slovetskii and T. V. Rakhimova},
title = {Mathematical Modeling of the Plasma-Chemical Pyrolysis of Methane},
journal = {High Energy Chemistry},
year = {2002},
volume = {36},
publisher = {Pleiades Publishing},
month = {dec},
url = {https://doi.org/10.1023/a:1013600628538},
number = {1},
pages = {44--52},
doi = {10.1023/a:1013600628538}
}
Cite this
MLA
Copy
Slovetskii, D. I., et al. “Mathematical Modeling of the Plasma-Chemical Pyrolysis of Methane.” High Energy Chemistry, vol. 36, no. 1, Dec. 2002, pp. 44-52. https://doi.org/10.1023/a:1013600628538.