Epoxidation of styrene with TBHP/O2 over ferrierite (FER) type molecular sieves
Publication type: Journal Article
Publication date: 1999-01-01
scimago Q2
wos Q3
SJR: 0.539
CiteScore: 4.9
Impact factor: 2.4
ISSN: 1011372X, 1572879X
General Chemistry
Catalysis
Abstract
Epoxidation of styrene over vanadium silicalite with ferrierite (FER) type topology is undertaken. Influence of temperature, pressure, various solvents and solvent to substrate mole ratio was investigated. Conversion increased with increase in temperature and pressure. Solvent to substrate mole ratio is found to play a crucial role in increasing the conversion and selectivity. Catalytic activity of V‐FER was compared with those of Ti‐FER, TS‐1 and Fe‐FER. In the case of V‐ and Ti‐ferrierite analogs, styrene oxide was the major product, whereas phenylacetaldehyde was the major product in the case of TS‐1. The catalyst could be recycled after washing by a suitable solvent such as acetone and showed no significant loss in catalytic activity.
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Anand R. et al. Epoxidation of styrene with TBHP/O2 over ferrierite (FER) type molecular sieves // Catalysis Letters. 1999. Vol. 62. No. 2/4. pp. 209-213.
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Anand R., Shevade S., Ahedi R., Mirajkar S., Rao B. S. Epoxidation of styrene with TBHP/O2 over ferrierite (FER) type molecular sieves // Catalysis Letters. 1999. Vol. 62. No. 2/4. pp. 209-213.
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RIS
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TY - JOUR
DO - 10.1023/a:1019099006237
UR - https://doi.org/10.1023/a:1019099006237
TI - Epoxidation of styrene with TBHP/O2 over ferrierite (FER) type molecular sieves
T2 - Catalysis Letters
AU - Anand, R
AU - Shevade, S.S
AU - Ahedi, R.K
AU - Mirajkar, S.P.
AU - Rao, B S
PY - 1999
DA - 1999/01/01
PB - Springer Nature
SP - 209-213
IS - 2/4
VL - 62
SN - 1011-372X
SN - 1572-879X
ER -
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BibTex (up to 50 authors)
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@article{1999_Anand,
author = {R Anand and S.S Shevade and R.K Ahedi and S.P. Mirajkar and B S Rao},
title = {Epoxidation of styrene with TBHP/O2 over ferrierite (FER) type molecular sieves},
journal = {Catalysis Letters},
year = {1999},
volume = {62},
publisher = {Springer Nature},
month = {jan},
url = {https://doi.org/10.1023/a:1019099006237},
number = {2/4},
pages = {209--213},
doi = {10.1023/a:1019099006237}
}
Cite this
MLA
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Anand, R., et al. “Epoxidation of styrene with TBHP/O2 over ferrierite (FER) type molecular sieves.” Catalysis Letters, vol. 62, no. 2/4, Jan. 1999, pp. 209-213. https://doi.org/10.1023/a:1019099006237.