Thermocapillary central lamella recess during droplet impacts onto a heated wall

We experimentally observe a new phenomenon, the formation of a toroidal region of lower film thickness in the center of the lamella formed during high Weber number water droplet impacts onto smooth heated walls. This region forms around the air bubble, which is entrapped during the initial impact phase at the impact center. Our study encompasses a variation of the droplet size, impact velocity, surface wettability and temperature. We show how this phenomenon can be explained considering a two-step process involving thermocapillary convection in two separate regions: The temperature gradient along the surface of the entrapped air bubble caused by heat conduction induces flow that pumps warmer liquid to the lamella-ambient interface due to the Marangoni effect. The non-uniform temperature distribution along it then causes fluid acceleration in the radial direction, depleting the fluid volume around the bubble in a self-amplifying manner. We use direct numerical simulations of a stagnant liquid film with an enclosed bubble at the wall to confirm this theory.