Springer Nature
Nature
,  volume 144 ,  issue 3655 ,  pages 865

Structure of the Dimeric Forms of o-Isopropenyl-phenols

Publication type: Journal Article
Publication date: 1939-11-01
Springer Nature
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SJR: 18.288
CiteScore: 78.1
Impact factor: 48.5
ISSN: 00280836, 14764687
Multidisciplinary
Abstract
o-HYDROXYisoPROPENYL compounds, for example (1), readily polymerize to dimeric forms on long standing or on treatment with hydrogen chloride1. These dimerides can be distilled under diminished pressure and are generally resinous at ordinary temperature, but they yield well crystalline monoacetyl derivatives, and contain only one free hydroxyl group. They exhibit only extremely feeble phenolic properties, are saturated, and depolymerize when distilled under atmospheric pressure. A study of the dimeric form of isopropenyl-m-cresol (I)2 has shown that it yields on vigorous oxidation with potassium permanganate a stable carboxylic acid, C13H17O.CO2H, by degradation of a m-cresyl group to a carboxyl group.
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GOST |
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GOST Copy
Baker W., Besly D. M. Structure of the Dimeric Forms of o-Isopropenyl-phenols // Nature. 1939. Vol. 144. No. 3655. p. 865.
GOST all authors (up to 50) Copy
Baker W., Besly D. M. Structure of the Dimeric Forms of o-Isopropenyl-phenols // Nature. 1939. Vol. 144. No. 3655. p. 865.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1038/144865a0
UR - https://doi.org/10.1038/144865a0
TI - Structure of the Dimeric Forms of o-Isopropenyl-phenols
T2 - Nature
AU - Baker, Wilson
AU - Besly, D M
PY - 1939
DA - 1939/11/01
PB - Springer Nature
SP - 865
IS - 3655
VL - 144
SN - 0028-0836
SN - 1476-4687
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{1939_Baker,
author = {Wilson Baker and D M Besly},
title = {Structure of the Dimeric Forms of o-Isopropenyl-phenols},
journal = {Nature},
year = {1939},
volume = {144},
publisher = {Springer Nature},
month = {nov},
url = {https://doi.org/10.1038/144865a0},
number = {3655},
pages = {865},
doi = {10.1038/144865a0}
}
MLA
Cite this
MLA Copy
Baker, Wilson, and D M Besly. “Structure of the Dimeric Forms of o-Isopropenyl-phenols.” Nature, vol. 144, no. 3655, Nov. 1939, p. 865. https://doi.org/10.1038/144865a0.