Nature

, том 202 , издание 4927 , страницы 80

Heat of Formation of Difluoromethylene : Evidence from the Kinetics of Pyrolysis of Chlorodifluoromethane

Тип публикации: Journal Article

Дата публикации: 1964-04-01

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ISSN: 00280836, 14764687

DOI: 10.1038/202080b0

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THE thermochemistry of difluoromethylene is of considerable interest in view of the apparent high stability of this radical. The largest (least negative) value for the heat of formation of difluoromethylene requires an unexpectedly low value for the dissociation energy of the carbon–carbon bond in tetrafluoroethylene1. Other estimates of the heat of formation of the radical suggest an even greater stability with respect to tetrafluoroethylene2.

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Gozzo F., Patrick C. R. Heat of Formation of Difluoromethylene : Evidence from the Kinetics of Pyrolysis of Chlorodifluoromethane // Nature. 1964. Vol. 202. No. 4927. p. 80.

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Gozzo F., Patrick C. R. Heat of Formation of Difluoromethylene : Evidence from the Kinetics of Pyrolysis of Chlorodifluoromethane // Nature. 1964. Vol. 202. No. 4927. p. 80.

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TY - JOUR

DO - 10.1038/202080b0

UR - https://doi.org/10.1038/202080b0

TI - Heat of Formation of Difluoromethylene : Evidence from the Kinetics of Pyrolysis of Chlorodifluoromethane

T2 - Nature

AU - Gozzo, F.

AU - Patrick, C R

PY - 1964

DA - 1964/04/01

PB - Springer Nature

SP - 80

IS - 4927

VL - 202

SN - 0028-0836

SN - 1476-4687

ER -

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@article{1964_Gozzo,

author = {F. Gozzo and C R Patrick},

title = {Heat of Formation of Difluoromethylene : Evidence from the Kinetics of Pyrolysis of Chlorodifluoromethane},

journal = {Nature},

year = {1964},

volume = {202},

publisher = {Springer Nature},

month = {apr},

url = {https://doi.org/10.1038/202080b0},

number = {4927},

pages = {80},

doi = {10.1038/202080b0}

}

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Gozzo, F., and C R Patrick. “Heat of Formation of Difluoromethylene : Evidence from the Kinetics of Pyrolysis of Chlorodifluoromethane.” Nature, vol. 202, no. 4927, Apr. 1964, p. 80. https://doi.org/10.1038/202080b0.

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