Open Access
NPG Asia Materials, volume 9, issue 9, pages e433
Fluorine-functionalized metal–organic frameworks and porous coordination polymers
Publication type: Journal Article
Publication date: 2017-09-29
Journal:
NPG Asia Materials
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 9.7
ISSN: 18844049, 18844057
Condensed Matter Physics
General Materials Science
Modeling and Simulation
Abstract
Fluorine, the element with the highest electronegativity and low electric polarizability, can produce a variety of characteristics, including specific adsorption sites for molecules as well as flexibility to the host materials. In this review, we will introduce fluorine-functionalized metal–organic frameworks/porous coordination polymers that show unique and unprecedented structures, structural transformations, and gas and vapor adsorption/separation properties derived from the fluorine characteristics. Adding chemistry's most electronegative atom to porous polymer networks may lead to gas-specific filters capable of flexible ‘breathing’. The tunable activity of metal–organic frameworks towards specific guest molecules, such as drugs or pollutants, has led to a flurry of recent research reports. Shin–ichiro Noro and Takayoshi Nakamura from Hokkaido University in Japan review these findings to show the potential of fluorinated building blocks in porous polymers. The hydrophobic nature and strong bond polarity of organic–fluorine units induce preferential adsorption sites and hydrophobic character useful for oil spill clean-ups. Alternatively, combining inorganic fluorine anions with neutral molecules produces weaker network bonds that easily slip and deform in certain directions. Framework flexibilities and other properties including luminescent emission for sensors are adjustable through appropriate organic or inorganic fluorine units. Fluorine, the element with the highest electronegativity and low electric polarizability, can produce a variety of characteristics, including specific adsorption sites for molecules as well as flexibility to the host materials. In this review, we will introduce fluorine-functionalized metal–organic frameworks/porous coordination polymers that show unique and unprecedented structures, structural transformations, and gas and vapor adsorption/separation properties derived from the fluorine characteristics.
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Citations by publishers
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1 publication, 1.01%
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Noro S., Nakamura T. Fluorine-functionalized metal–organic frameworks and porous coordination polymers // NPG Asia Materials. 2017. Vol. 9. No. 9. p. e433.
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Noro S., Nakamura T. Fluorine-functionalized metal–organic frameworks and porous coordination polymers // NPG Asia Materials. 2017. Vol. 9. No. 9. p. e433.
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TY - JOUR
DO - 10.1038/am.2017.165
UR - https://doi.org/10.1038/am.2017.165
TI - Fluorine-functionalized metal–organic frameworks and porous coordination polymers
T2 - NPG Asia Materials
AU - Noro, Shin-ichiro
AU - Nakamura, Takayoshi
PY - 2017
DA - 2017/09/29 00:00:00
PB - Springer Nature
SP - e433
IS - 9
VL - 9
SN - 1884-4049
SN - 1884-4057
ER -
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@article{2017_Noro,
author = {Shin-ichiro Noro and Takayoshi Nakamura},
title = {Fluorine-functionalized metal–organic frameworks and porous coordination polymers},
journal = {NPG Asia Materials},
year = {2017},
volume = {9},
publisher = {Springer Nature},
month = {sep},
url = {https://doi.org/10.1038/am.2017.165},
number = {9},
pages = {e433},
doi = {10.1038/am.2017.165}
}
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Noro, Shin-ichiro, et al. “Fluorine-functionalized metal–organic frameworks and porous coordination polymers.” NPG Asia Materials, vol. 9, no. 9, Sep. 2017, p. e433. https://doi.org/10.1038/am.2017.165.