Open Access
Nature Communications, volume 5, issue 1, publication number 4475
High-mobility transport anisotropy and linear dichroism in few-layer black phosphorus
Publication type: Journal Article
Publication date: 2014-07-21
Journal:
Nature Communications
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 16.6
ISSN: 20411723, 20411723
PubMed ID:
25042376
General Chemistry
General Biochemistry, Genetics and Molecular Biology
General Physics and Astronomy
Abstract
Two-dimensional crystals are emerging materials for nanoelectronics. Development of the field requires candidate systems with both a high carrier mobility and, in contrast to graphene, a sufficiently large electronic bandgap. Here we present a detailed theoretical investigation of the atomic and electronic structure of few-layer black phosphorus (BP) to predict its electrical and optical properties. This system has a direct bandgap, tunable from 1.51 eV for a monolayer to 0.59 eV for a five-layer sample. We predict that the mobilities are hole-dominated, rather high and highly anisotropic. The monolayer is exceptional in having an extremely high hole mobility (of order 10,000 cm2 V−1 s−1) and anomalous elastic properties which reverse the anisotropy. Light absorption spectra indicate linear dichroism between perpendicular in-plane directions, which allows optical determination of the crystalline orientation and optical activation of the anisotropic transport properties. These results make few-layer BP a promising candidate for future electronics. Two-dimensional (2D) materials with a large electronic bandgap in addition to high carrier mobility are required for future nanoelectronics. Here, the authors present a theoretical investigation of black phosphorous, a new category of 2D semiconductor with high potential for nanoelectronic applications.
Top-30
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Citations by publishers
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Elsevier
665 publications, 18.34%
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American Chemical Society (ACS)
555 publications, 15.31%
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Royal Society of Chemistry (RSC)
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Wiley
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Springer Nature
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American Physical Society (APS)
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American Institute of Physics (AIP)
147 publications, 4.06%
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Multidisciplinary Digital Publishing Institute (MDPI)
73 publications, 2.01%
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IEEE
48 publications, 1.32%
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Optical Society of America
43 publications, 1.19%
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Chinese Physical Society
21 publications, 0.58%
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Taylor & Francis
16 publications, 0.44%
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American Association for the Advancement of Science (AAAS)
16 publications, 0.44%
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Walter de Gruyter
13 publications, 0.36%
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Japan Society of Applied Physics
9 publications, 0.25%
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World Scientific
8 publications, 0.22%
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Science in China Press
7 publications, 0.19%
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SPIE
6 publications, 0.17%
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Frontiers Media S.A.
5 publications, 0.14%
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Proceedings of the National Academy of Sciences (PNAS)
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4 publications, 0.11%
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Qiao J. et al. High-mobility transport anisotropy and linear dichroism in few-layer black phosphorus // Nature Communications. 2014. Vol. 5. No. 1. 4475
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Qiao J., Kong X., Hu Z. X., Yang F., Ji W. High-mobility transport anisotropy and linear dichroism in few-layer black phosphorus // Nature Communications. 2014. Vol. 5. No. 1. 4475
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TY - JOUR
DO - 10.1038/ncomms5475
UR - https://doi.org/10.1038/ncomms5475
TI - High-mobility transport anisotropy and linear dichroism in few-layer black phosphorus
T2 - Nature Communications
AU - Qiao, Jingsi
AU - Kong, Xianghua
AU - Hu, Zhi Xin
AU - Yang, Feng
AU - Ji, Wei
PY - 2014
DA - 2014/07/21 00:00:00
PB - Springer Nature
IS - 1
VL - 5
PMID - 25042376
SN - 2041-1723
SN - 2041-1723
ER -
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@article{2014_Qiao,
author = {Jingsi Qiao and Xianghua Kong and Zhi Xin Hu and Feng Yang and Wei Ji},
title = {High-mobility transport anisotropy and linear dichroism in few-layer black phosphorus},
journal = {Nature Communications},
year = {2014},
volume = {5},
publisher = {Springer Nature},
month = {jul},
url = {https://doi.org/10.1038/ncomms5475},
number = {1},
doi = {10.1038/ncomms5475}
}