Nature Materials, volume 16, issue 5, pages 572-579

Negating interfacial impedance in garnet-based solid-state Li metal batteries

Xiaogang Han ¹

Yunhui Gong ¹

Kun Fu ¹

Xingfeng He ¹

Gregory T. Hitz ¹

Jiaqi Dai ¹

Alex Pearse ^{1, 2}

Boyang Liu ¹

Howard Wang ¹

Gary Rubloff ^{1, 2}

Yifei Mo ¹

Venkataraman Thangadurai ³

Eric D. Wachsman ¹

Liangbing Hu ¹

Hide authors affiliations Show authors affiliations: 3 affiliations

and Department of Materials Science and Engineering, University of Maryland Energy Research Center, University of Maryland, College Park, Maryland 20742, USA |

Institute for Systems Research, University of Maryland, College Park, Maryland 20742, USA |

Department of Chemistry, University of Calgary, 2500 University Drive Northwest, Calgary, Alberta T2N 1N4, Canada |

Publication type: Journal Article

Publication date: 2016-12-19

Springer Nature

Journal: Nature Materials

Quartile SCImago

Quartile WOS

Impact factor: 41.2

ISSN: 14761122, 14764660

DOI: 10.1038/nmat4821

Copy DOI

General Chemistry

Condensed Matter Physics

General Materials Science

Mechanical Engineering

Mechanics of Materials

Abstract

Garnet-type solid-state electrolytes have attracted extensive attention due to their high ionic conductivity, approaching 1 mS cm−1, excellent environmental stability, and wide electrochemical stability window, from lithium metal to ∼6 V. However, to date, there has been little success in the development of high-performance solid-state batteries using these exceptional materials, the major challenge being the high solid–solid interfacial impedance between the garnet electrolyte and electrode materials. In this work, we effectively address the large interfacial impedance between a lithium metal anode and the garnet electrolyte using ultrathin aluminium oxide (Al2O3) by atomic layer deposition. Li7La2.75Ca0.25Zr1.75Nb0.25O12 (LLCZN) is the garnet composition of choice in this work due to its reduced sintering temperature and increased lithium ion conductivity. A significant decrease of interfacial impedance, from 1,710 Ω cm2 to 1 Ω cm2, was observed at room temperature, effectively negating the lithium metal/garnet interfacial impedance. Experimental and computational results reveal that the oxide coating enables wetting of metallic lithium in contact with the garnet electrolyte surface and the lithiated-alumina interface allows effective lithium ion transport between the lithium metal anode and garnet electrolyte. We also demonstrate a working cell with a lithium metal anode, garnet electrolyte and a high-voltage cathode by applying the newly developed interface chemistry. Garnet-type electrolytes are attractive for lithium metal batteries due to their high ionic conductivity. A strategy to decrease interfacial impedance between a lithium metal anode and garnet electrolyte is found promising for all-solid-state batteries.

By date By citations

Top-30

Citations by journals

	20 40 60 80 100 120
ACS applied materials & interfaces	ACS applied materials & interfaces, 111, 6.8% ACS applied materials & interfaces 111 publications, 6.8%
Energy Storage Materials	Energy Storage Materials, 92, 5.64% Energy Storage Materials 92 publications, 5.64%
Advanced Energy Materials	Advanced Energy Materials, 81, 4.96% Advanced Energy Materials 81 publications, 4.96%
Journal of Materials Chemistry A	Journal of Materials Chemistry A, 74, 4.53% Journal of Materials Chemistry A 74 publications, 4.53%
Journal of Power Sources	Journal of Power Sources, 64, 3.92% Journal of Power Sources 64 publications, 3.92%
Advanced Functional Materials	Advanced Functional Materials, 58, 3.55% Advanced Functional Materials 58 publications, 3.55%
Advanced Materials	Advanced Materials, 52, 3.19% Advanced Materials 52 publications, 3.19%
ACS Energy Letters	ACS Energy Letters, 41, 2.51% ACS Energy Letters 41 publications, 2.51%
ACS Applied Energy Materials	ACS Applied Energy Materials, 39, 2.39% ACS Applied Energy Materials 39 publications, 2.39%
Chemical Engineering Journal	Chemical Engineering Journal, 34, 2.08% Chemical Engineering Journal 34 publications, 2.08%
Electrochimica Acta	Electrochimica Acta, 32, 1.96% Electrochimica Acta 32 publications, 1.96%
Chemistry of Materials	Chemistry of Materials, 31, 1.9% Chemistry of Materials 31 publications, 1.9%
Journal of the Electrochemical Society	Journal of the Electrochemical Society, 31, 1.9% Journal of the Electrochemical Society 31 publications, 1.9%
Angewandte Chemie - International Edition	Angewandte Chemie - International Edition, 28, 1.72% Angewandte Chemie - International Edition 28 publications, 1.72%
Angewandte Chemie	Angewandte Chemie, 28, 1.72% Angewandte Chemie 28 publications, 1.72%
Small	Small, 26, 1.59% Small 26 publications, 1.59%
Nano Energy	Nano Energy, 26, 1.59% Nano Energy 26 publications, 1.59%
Nano Letters	Nano Letters, 21, 1.29% Nano Letters 21 publications, 1.29%
Energy and Environmental Science	Energy and Environmental Science, 21, 1.29% Energy and Environmental Science 21 publications, 1.29%
Joule	Joule, 19, 1.16% Joule 19 publications, 1.16%
Solid State Ionics	Solid State Ionics, 15, 0.92% Solid State Ionics 15 publications, 0.92%
Ceramics International	Ceramics International, 15, 0.92% Ceramics International 15 publications, 0.92%
Electrochemical Energy Reviews	Electrochemical Energy Reviews, 14, 0.86% Electrochemical Energy Reviews 14 publications, 0.86%
Materials Today	Materials Today, 14, 0.86% Materials Today 14 publications, 0.86%
Batteries & Supercaps	Batteries & Supercaps, 14, 0.86% Batteries & Supercaps 14 publications, 0.86%
Journal of Alloys and Compounds	Journal of Alloys and Compounds, 13, 0.8% Journal of Alloys and Compounds 13 publications, 0.8%
Journal of the American Chemical Society	Journal of the American Chemical Society, 12, 0.74% Journal of the American Chemical Society 12 publications, 0.74%
Nature Communications	Nature Communications, 12, 0.74% Nature Communications 12 publications, 0.74%
Chemical Reviews	Chemical Reviews, 11, 0.67% Chemical Reviews 11 publications, 0.67%
	20 40 60 80 100 120

Citations by publishers

	50 100 150 200 250 300 350 400 450 500
Elsevier	Elsevier, 480, 29.41% Elsevier 480 publications, 29.41%
Wiley	Wiley, 390, 23.9% Wiley 390 publications, 23.9%
American Chemical Society (ACS)	American Chemical Society (ACS), 303, 18.57% American Chemical Society (ACS) 303 publications, 18.57%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 160, 9.8% Royal Society of Chemistry (RSC) 160 publications, 9.8%
Springer Nature	Springer Nature, 101, 6.19% Springer Nature 101 publications, 6.19%
The Electrochemical Society	The Electrochemical Society, 31, 1.9% The Electrochemical Society 31 publications, 1.9%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 29, 1.78% Multidisciplinary Digital Publishing Institute (MDPI) 29 publications, 1.78%
American Association for the Advancement of Science (AAAS)	American Association for the Advancement of Science (AAAS), 11, 0.67% American Association for the Advancement of Science (AAAS) 11 publications, 0.67%
IOP Publishing	IOP Publishing, 10, 0.61% IOP Publishing 10 publications, 0.61%
Frontiers Media S.A.	Frontiers Media S.A., 8, 0.49% Frontiers Media S.A. 8 publications, 0.49%
Cambridge University Press	Cambridge University Press, 8, 0.49% Cambridge University Press 8 publications, 0.49%
Nonferrous Metals Society of China	Nonferrous Metals Society of China, 8, 0.49% Nonferrous Metals Society of China 8 publications, 0.49%
OAE Publishing Inc.	OAE Publishing Inc., 8, 0.49% OAE Publishing Inc. 8 publications, 0.49%
American Institute of Physics (AIP)	American Institute of Physics (AIP), 5, 0.31% American Institute of Physics (AIP) 5 publications, 0.31%
Chinese Physical Society	Chinese Physical Society, 5, 0.31% Chinese Physical Society 5 publications, 0.31%
American Vacuum Society	American Vacuum Society, 4, 0.25% American Vacuum Society 4 publications, 0.25%
Taylor & Francis	Taylor & Francis, 4, 0.25% Taylor & Francis 4 publications, 0.25%
American Physical Society (APS)	American Physical Society (APS), 3, 0.18% American Physical Society (APS) 3 publications, 0.18%
Oxford University Press	Oxford University Press, 3, 0.18% Oxford University Press 3 publications, 0.18%
ASME	ASME, 2, 0.12% ASME 2 publications, 0.12%
World Scientific	World Scientific, 2, 0.12% World Scientific 2 publications, 0.12%
Korean Ceramic Society	Korean Ceramic Society, 2, 0.12% Korean Ceramic Society 2 publications, 0.12%
Tsinghua University Press	Tsinghua University Press, 2, 0.12% Tsinghua University Press 2 publications, 0.12%
Proceedings of the National Academy of Sciences (PNAS)	Proceedings of the National Academy of Sciences (PNAS), 2, 0.12% Proceedings of the National Academy of Sciences (PNAS) 2 publications, 0.12%
IEEE	IEEE, 2, 0.12% IEEE 2 publications, 0.12%
Research Square Platform LLC	Research Square Platform LLC, 2, 0.12% Research Square Platform LLC 2 publications, 0.12%
Bentham Science	Bentham Science, 1, 0.06% Bentham Science 1 publication, 0.06%
Canadian Science Publishing	Canadian Science Publishing, 1, 0.06% Canadian Science Publishing 1 publication, 0.06%
The Royal Society	The Royal Society, 1, 0.06% The Royal Society 1 publication, 0.06%
	50 100 150 200 250 300 350 400 450 500

We do not take into account publications without a DOI.
Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
Statistics recalculated weekly.

{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2017,2018,2019,2020,2021,2022,2023,2024],"ids":[0,0,0,0,0,0,0,0],"codes":[0,0,0,0,0,0,0,0],"imageUrls":["","","","","","","",""],"datasets":[{"label":"Citations number","data":[75,188,260,280,240,245,201,142],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":["4.6","11.52","15.93","17.16","14.71","15.01","12.32","8.7"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["ACS applied materials & interfaces","Energy Storage Materials","Advanced Energy Materials","Journal of Materials Chemistry A","Journal of Power Sources","Advanced Functional Materials","Advanced Materials","ACS Energy Letters","ACS Applied Energy Materials","Chemical Engineering Journal","Electrochimica Acta","Chemistry of Materials","Journal of the Electrochemical Society","Angewandte Chemie - International Edition","Angewandte Chemie","Small","Nano Energy","Nano Letters","Energy and Environmental Science","Joule","Solid State Ionics","Ceramics International","Electrochemical Energy Reviews","Materials Today","Batteries & Supercaps","Journal of Alloys and Compounds","Journal of the American Chemical Society","Nature Communications","Chemical Reviews"],"ids":[1458,3858,22475,14919,14844,7715,25159,9022,6419,16275,15613,6428,5297,19215,25450,9872,23236,10312,10138,22630,12542,15103,25884,5179,26456,4015,4813,3231,13718],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/s6nfxitVCZUsdJiJZESaAXqdmMJxom8q4Ps6ayL2_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp"],"datasets":[{"label":"","data":[111,92,81,74,64,58,52,41,39,34,32,31,31,28,28,26,26,21,21,19,15,15,14,14,14,13,12,12,11],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[6.8,5.64,4.96,4.53,3.92,3.55,3.19,2.51,2.39,2.08,1.96,1.9,1.9,1.72,1.72,1.59,1.59,1.29,1.29,1.16,0.92,0.92,0.86,0.86,0.86,0.8,0.74,0.74,0.67],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["Elsevier","Wiley","American Chemical Society (ACS)","Royal Society of Chemistry (RSC)","Springer Nature","The Electrochemical Society","Multidisciplinary Digital Publishing Institute (MDPI)","American Association for the Advancement of Science (AAAS)","IOP Publishing","Frontiers Media S.A.","Cambridge University Press","Nonferrous Metals Society of China","OAE Publishing Inc.","American Institute of Physics (AIP)","Chinese Physical Society","American Vacuum Society","Taylor & Francis","American Physical Society (APS)","Oxford University Press","ASME","World Scientific","Korean Ceramic Society","Tsinghua University Press","Proceedings of the National Academy of Sciences (PNAS)","IEEE","Research Square Platform LLC","Bentham Science","Canadian Science Publishing","The Royal Society"],"ids":[17,11,40,123,8,6916,202,189,2075,208,1,1585,7181,250,3809,4511,18,1539,19,6977,23,1949,1836,162,6953,9418,39,6942,259],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/s6nfxitVCZUsdJiJZESaAXqdmMJxom8q4Ps6ayL2_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/s10mcsCV4OAUg9O2KrqOquQC0PhyLMI8hUUkuflM_medium.webp","\/storage\/images\/resized\/LsKy6OnmmmRGcAU6CZgWQvNiP1polbaSLNrN7zqj_medium.webp","\/storage\/images\/resized\/4QWA67eqfcfyOiA8Wk7YnqroHFqQbTsmDJUYTCTg_medium.webp","\/storage\/images\/resized\/cF81zWlLdkmYekymGuDcSdvgBGNKaIDoMoeJtHS1_medium.webp","","\/storage\/images\/resized\/0oGA3odz6rRHYyWD8vQnHiPJ8KIaP1PtNoJm7RE1_medium.webp","\/storage\/images\/resized\/ARM4e6URKRsbRZvIF0vFis9DjxGloBjnBYJXbHmZ_medium.webp","\/storage\/images\/resized\/uHl9M7oE4uFd6rEwxtu87cdHS4Etul2pdLbot8Qu_medium.webp","\/storage\/images\/resized\/uCIAsivcf0PwzbBKNlcVk4osRd48viDZSveDRvyx_medium.webp","\/storage\/images\/resized\/5YZtvLvkPZuc2JHOaZsjCvGSHFCuC3drUwN3YAc5_medium.webp","\/storage\/images\/resized\/nrK64iXHTzj43wMrfN1ZoUQ0vanswGzWPN45K3jA_medium.webp","\/storage\/images\/resized\/yNSijlgQghQF53VZuyFLA30CKDe4j3HK74Vtpnxa_medium.webp","\/storage\/images\/resized\/yKbGpvfNleUTiwBfKt4XcIFlZMo3HgWv1KKVqn4g_medium.webp","\/storage\/images\/resized\/jZQkhOOcY9wrGwZm7XGRwMe8H7fThQu3KamISuun_medium.webp","","\/storage\/images\/resized\/ZBf59wI1SMgSL89rU8cJXRfzrfAz8slfIClYmcuk_medium.webp","\/storage\/images\/resized\/mxFdPe9qujsfvfYfcN0QOclAiYORFb0xrRlwV8gs_medium.webp","\/storage\/images\/resized\/6scCJegesojp2jubwY3uKCzTAmgsaH2GIFlg6Hfk_medium.webp","","\/storage\/images\/resized\/doUaFUZdxUEQjLi1TwZjGHi8HXYNWWSk04dSC6Xh_medium.webp","\/storage\/images\/resized\/qZfu8vVyaDIo81Au73p6SNE8AGGzf73yfiTC33bu_medium.webp","\/storage\/images\/resized\/BHBStD1OkQqtKFRRjS5njgNe7bXCAEgaDQVK7GTA_medium.webp"],"datasets":[{"label":"","data":[480,390,303,160,101,31,29,11,10,8,8,8,8,5,5,4,4,3,3,2,2,2,2,2,2,2,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[29.41,23.9,18.57,9.8,6.19,1.9,1.78,0.67,0.61,0.49,0.49,0.49,0.49,0.31,0.31,0.25,0.25,0.18,0.18,0.12,0.12,0.12,0.12,0.12,0.12,0.12,0.06,0.06,0.06],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartiles":{"type":"bar","data":{"show":true,"labels":[2017,2018,2019,2020,2021,2022,2023,2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,0,0,1,0,1,0,0],"percentage":["0","0","0","0.06","0","0.06","0","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[4,2,0,7,0,3,2,2],"percentage":["0.25","0.12","0","0.43","0","0.18","0.12","0.12"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[3,5,15,19,18,16,15,5],"percentage":["0.18","0.31","0.92","1.16","1.1","0.98","0.92","0.31"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[68,180,230,248,215,204,169,117],"percentage":["4.17","11.03","14.09","15.2","13.17","12.5","10.36","7.17"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[0,1,15,5,7,21,15,18],"percentage":["0","0.06","0.92","0.31","0.43","1.29","0.92","1.1"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by SCImago per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartilesWs":{"type":"bar","data":{"show":true,"labels":[2017,2018,2019,2020,2021,2022,2023,2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,1,1,7,3,4,1,1],"percentage":["0","0.06","0.06","0.43","0.18","0.25","0.06","0.06"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[1,1,4,7,5,5,6,1],"percentage":["0.06","0.06","0.25","0.43","0.31","0.31","0.37","0.06"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[14,28,40,40,29,30,37,13],"percentage":["0.86","1.72","2.45","2.45","1.78","1.84","2.27","0.8"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[54,154,196,212,187,179,141,104],"percentage":["3.31","9.44","12.01","12.99","11.46","10.97","8.64","6.37"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[6,4,19,14,16,27,16,23],"percentage":["0.37","0.25","1.16","0.86","0.98","1.65","0.98","1.41"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by WoS per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}

Are you a researcher?

Create a profile to get free access to personal recommendations for colleagues and new articles.

Metrics

Cite this

GOST |

Cite this

GOST Copy

Han X. et al. Negating interfacial impedance in garnet-based solid-state Li metal batteries // Nature Materials. 2016. Vol. 16. No. 5. pp. 572-579.

GOST all authors (up to 50) Copy

Han X., Gong Y., Fu K., He X., Hitz G. T., Dai J., Pearse A., Liu B., Wang H., Rubloff G., Mo Y., Thangadurai V., Wachsman E. D., Hu L. Negating interfacial impedance in garnet-based solid-state Li metal batteries // Nature Materials. 2016. Vol. 16. No. 5. pp. 572-579.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1038/nmat4821

UR - https://doi.org/10.1038/nmat4821

TI - Negating interfacial impedance in garnet-based solid-state Li metal batteries

T2 - Nature Materials

AU - Han, Xiaogang

AU - Gong, Yunhui

AU - Fu, Kun

AU - He, Xingfeng

AU - Hitz, Gregory T.

AU - Dai, Jiaqi

AU - Pearse, Alex

AU - Liu, Boyang

AU - Wang, Howard

AU - Rubloff, Gary

AU - Mo, Yifei

AU - Thangadurai, Venkataraman

AU - Wachsman, Eric D.

AU - Hu, Liangbing

PY - 2016

DA - 2016/12/19 00:00:00

PB - Springer Nature

SP - 572-579

IS - 5

VL - 16

SN - 1476-1122

SN - 1476-4660

ER -

BibTex |

Cite this

BibTex Copy

@article{2016_Han,

author = {Xiaogang Han and Yunhui Gong and Kun Fu and Xingfeng He and Gregory T. Hitz and Jiaqi Dai and Alex Pearse and Boyang Liu and Howard Wang and Gary Rubloff and Yifei Mo and Venkataraman Thangadurai and Eric D. Wachsman and Liangbing Hu},

title = {Negating interfacial impedance in garnet-based solid-state Li metal batteries},

journal = {Nature Materials},

year = {2016},

volume = {16},

publisher = {Springer Nature},

month = {dec},

url = {https://doi.org/10.1038/nmat4821},

number = {5},

pages = {572--579},

doi = {10.1038/nmat4821}

}

MLA

Cite this

MLA Copy

Han, Xiaogang, et al. “Negating interfacial impedance in garnet-based solid-state Li metal batteries.” Nature Materials, vol. 16, no. 5, Dec. 2016, pp. 572-579. https://doi.org/10.1038/nmat4821.

Found error?

Publisher

Springer Nature

Journal

Nature Materials

Quartile SCImago

Quartile WOS

Impact factor

41.2

ISSN

14761122 (Print)
14764660 (Electronic)