Open Access
Nature Communications, volume 14, issue 1, publication number 501
A hydrophobic Cu/Cu2O sheet catalyst for selective electroreduction of CO to ethanol
Ma Guifeng
1
,
Yan Huang
1
,
Stoian Dragos
3
,
Zhang Jie
3
,
Yang Shuliang
4
,
Luo Wen
5
,
Jiang Mengying
1
,
Li Shumu
6
,
Chen Chunjun
7, 8
,
Syzgantseva Maria A.
2
,
Yan Sen
1
,
Chen Ningyu
1
,
Peng Li
1
,
Li Jun
1, 9, 10
,
Han Buxing
7, 8
6
Institute of Chemistry, Chinese Academy of Sciences, Beijing Mass Spectrum Center, Beijing, China
|
8
Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Colloid, Interface and Chemical Thermodynamics, CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, PR China
|
10
Collaborative Innovation Center of Chemistry for Energy Materials, Xiamen, China
|
Publication type: Journal Article
Publication date: 2023-01-31
Journal:
Nature Communications
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 16.6
ISSN: 20411723
General Chemistry
General Biochemistry, Genetics and Molecular Biology
Multidisciplinary
General Physics and Astronomy
Abstract
Electrocatalytic reduction of carbon monoxide into fuels or chemicals with two or more carbons is very attractive due to their high energy density and economic value. Herein we demonstrate the synthesis of a hydrophobic Cu/Cu2O sheet catalyst with hydrophobic n-butylamine layer and its application in CO electroreduction. The CO reduction on this catalyst produces two or more carbon products with a Faradaic efficiency of 93.5% and partial current density of 151 mA cm−2 at the potential of −0.70 V versus a reversible hydrogen electrode. A Faradaic efficiency of 68.8% and partial current density of 111 mA cm−2 for ethanol were reached, which is very high in comparison to all previous reports of CO2/CO electroreduction with a total current density higher than 10 mA cm−2. The as-prepared catalyst also showed impressive stability that the activity and selectivity for two or more carbon products could remain even after 100 operating hours. This work opens a way for efficient electrocatalytic conversion of CO2/CO to liquid fuels.
Citations by journals
|
1
2
3
|
|
|
ACS Catalysis
|
ACS Catalysis
3 publications, 12%
|
|
Chemical Engineering Journal
|
Chemical Engineering Journal
3 publications, 12%
|
|
ChemCatChem
|
ChemCatChem
2 publications, 8%
|
|
ACS Materials Letters
|
ACS Materials Letters
1 publication, 4%
|
|
Dalton Transactions
|
Dalton Transactions
1 publication, 4%
|
|
Next Energy
|
Next Energy
1 publication, 4%
|
|
Journal of Environmental Management
|
Journal of Environmental Management
1 publication, 4%
|
|
Nature Communications
|
Nature Communications
1 publication, 4%
|
|
Journal of Materials Chemistry A
|
Journal of Materials Chemistry A
1 publication, 4%
|
|
Environmental Functional Materials
|
Environmental Functional Materials
1 publication, 4%
|
|
Applied Catalysis B: Environmental
|
Applied Catalysis B: Environmental
1 publication, 4%
|
|
Advanced Functional Materials
|
Advanced Functional Materials
1 publication, 4%
|
|
Small
|
Small
1 publication, 4%
|
|
Advanced Energy Materials
|
Advanced Energy Materials
1 publication, 4%
|
|
Journal of Alloys and Compounds
|
Journal of Alloys and Compounds
1 publication, 4%
|
|
Chinese Chemical Letters
|
Chinese Chemical Letters
1 publication, 4%
|
|
ACS Sustainable Chemistry and Engineering
|
ACS Sustainable Chemistry and Engineering
1 publication, 4%
|
|
Coordination Chemistry Reviews
|
Coordination Chemistry Reviews
1 publication, 4%
|
|
Next Materials
|
Next Materials
1 publication, 4%
|
|
1
2
3
|
Citations by publishers
|
2
4
6
8
10
12
|
|
|
Elsevier
|
Elsevier
11 publications, 44%
|
|
American Chemical Society (ACS)
|
American Chemical Society (ACS)
5 publications, 20%
|
|
Wiley
|
Wiley
5 publications, 20%
|
|
Royal Society of Chemistry (RSC)
|
Royal Society of Chemistry (RSC)
2 publications, 8%
|
|
Springer Nature
|
Springer Nature
1 publication, 4%
|
|
2
4
6
8
10
12
|
- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2023,2024],"ids":[0,0],"codes":[0,0],"imageUrls":["",""],"datasets":[{"label":"Citations number","data":[13,12],"backgroundColor":["#3B82F6","#3B82F6"],"percentage":["52","48"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["ACS Catalysis","Chemical Engineering Journal","ChemCatChem","ACS Materials Letters","Dalton Transactions","Next Energy","Journal of Environmental Management","Nature Communications","Journal of Materials Chemistry A","Environmental Functional Materials","Applied Catalysis B: Environmental","Advanced Functional Materials","Small","Advanced Energy Materials","Journal of Alloys and Compounds","Chinese Chemical Letters","ACS Sustainable Chemistry and Engineering","Coordination Chemistry Reviews","Next Materials"],"ids":[4873,16275,10149,13131,8473,35588,19717,3231,14919,32649,18270,7715,9872,22475,4015,20341,18886,13437,36103],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp"],"datasets":[{"label":"","data":[3,3,2,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[12,12,8,4,4,4,4,4,4,4,4,4,4,4,4,4,4,4,4],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["Elsevier","American Chemical Society (ACS)","Wiley","Royal Society of Chemistry (RSC)","Springer Nature"],"ids":[17,40,11,123,8],"codes":[0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp"],"datasets":[{"label":"","data":[11,5,5,2,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[44,20,20,8,4],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}
Metrics
Cite this
GOST |
RIS |
BibTex
Cite this
GOST
Copy
Ma G. et al. A hydrophobic Cu/Cu2O sheet catalyst for selective electroreduction of CO to ethanol // Nature Communications. 2023. Vol. 14. No. 1. 501
GOST all authors (up to 50)
Copy
Ma G., Syzgantseva O. A., Yan H., Stoian D., Zhang J., Yang S., Luo W., Jiang M., Li S., Chen C., Syzgantseva M. A., Yan S., Chen N., Peng L., Li J., Han B. A hydrophobic Cu/Cu2O sheet catalyst for selective electroreduction of CO to ethanol // Nature Communications. 2023. Vol. 14. No. 1. 501
Cite this
RIS
Copy
TY - JOUR
DO - 10.1038/s41467-023-36261-1
UR - https://doi.org/10.1038%2Fs41467-023-36261-1
TI - A hydrophobic Cu/Cu2O sheet catalyst for selective electroreduction of CO to ethanol
T2 - Nature Communications
AU - Ma, Guifeng
AU - Syzgantseva, Olga A.
AU - Yan, Huang
AU - Stoian, Dragos
AU - Zhang, Jie
AU - Yang, Shuliang
AU - Luo, Wen
AU - Jiang, Mengying
AU - Li, Shumu
AU - Chen, Chunjun
AU - Syzgantseva, Maria A.
AU - Yan, Sen
AU - Chen, Ningyu
AU - Peng, Li
AU - Li, Jun
AU - Han, Buxing
PY - 2023
DA - 2023/01/31 00:00:00
PB - Springer Nature
IS - 1
VL - 14
SN - 2041-1723
ER -
Cite this
BibTex
Copy
@article{2023_Ma,
author = {Guifeng Ma and Olga A. Syzgantseva and Huang Yan and Dragos Stoian and Jie Zhang and Shuliang Yang and Wen Luo and Mengying Jiang and Shumu Li and Chunjun Chen and Maria A. Syzgantseva and Sen Yan and Ningyu Chen and Li Peng and Jun Li and Buxing Han},
title = {A hydrophobic Cu/Cu2O sheet catalyst for selective electroreduction of CO to ethanol},
journal = {Nature Communications},
year = {2023},
volume = {14},
publisher = {Springer Nature},
month = {jan},
url = {https://doi.org/10.1038%2Fs41467-023-36261-1},
number = {1},
doi = {10.1038/s41467-023-36261-1}
}
Profiles