Dalton Transactions

, том 49 , издание 46 , страницы 16935-16945

Cyclometalated Ru(II) complexes with tunable redox and optical properties for dye-sensitized solar cells

Тип публикации: Journal Article

Дата публикации: 2020-10-28

Royal Society of Chemistry (RSC)

Dalton Transactions

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SJR: 0.653

CiteScore: 6

Impact factor: 3.3

ISSN: 14779226, 14779234

DOI: 10.1039/D0DT03564E

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PubMed ID: 33188375

Inorganic Chemistry

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Cyclometalated Ru(II) complexes with 2-arylbenzimidazole antenna ligands bearing electron-donor/withdrawing substituents and anchoring 4,4′-dimethoxycarbonyl-2,2′-bipyridine have been prepared and their structure, optical and electrochemical properties have been studied. The complexes possess enhanced light-harvesting characteristics compared to those of the standard N719 dye and absorb light up to 750 nm. In addition, they demonstrate reversible redox behavior with Ru3+/Ru2+ potentials being finely tuned by the change of the electron-donating ability of cyclometalated ligands. After a mild hydrolysis of dimethoxycarbonyl groups the excellent optical properties of the complexes remain unchanged and they show good efficiency when tested in dye-sensitized solar cells.

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Dalton Transactions	Dalton Transactions, 3, 16.67% Dalton Transactions 3 публикации, 16.67%
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya	Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 2, 11.11% Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya 2 публикации, 11.11%
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Inorganic Chemistry Frontiers	Inorganic Chemistry Frontiers, 1, 5.56% Inorganic Chemistry Frontiers 1 публикация, 5.56%
Russian Journal of Inorganic Chemistry	Russian Journal of Inorganic Chemistry, 1, 5.56% Russian Journal of Inorganic Chemistry 1 публикация, 5.56%
Coordination Chemistry Reviews	Coordination Chemistry Reviews, 1, 5.56% Coordination Chemistry Reviews 1 публикация, 5.56%
Free Radical Biology and Medicine	Free Radical Biology and Medicine, 1, 5.56% Free Radical Biology and Medicine 1 публикация, 5.56%
Журнал неорганической химии	Журнал неорганической химии, 1, 5.56% Журнал неорганической химии 1 публикация, 5.56%
Chinese Journal of Physics	Chinese Journal of Physics, 1, 5.56% Chinese Journal of Physics 1 публикация, 5.56%
Electronics (Switzerland)	Electronics (Switzerland), 1, 5.56% Electronics (Switzerland) 1 публикация, 5.56%
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Lavrova M. A. et al. Cyclometalated Ru(II) complexes with tunable redox and optical properties for dye-sensitized solar cells // Dalton Transactions. 2020. Vol. 49. No. 46. pp. 16935-16945.

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Lavrova M. A., Mishurinskiy S. A., Smirnov D. E., Kalle P., Krivogina E. V., Kozyukhin S. A., Emets V. V., Emets V. V., Mariasina S. S., Dolzhenko V. D., Bezzubov S. I. Cyclometalated Ru(II) complexes with tunable redox and optical properties for dye-sensitized solar cells // Dalton Transactions. 2020. Vol. 49. No. 46. pp. 16935-16945.

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TY - JOUR

DO - 10.1039/D0DT03564E

UR - https://xlink.rsc.org/?DOI=D0DT03564E

TI - Cyclometalated Ru(II) complexes with tunable redox and optical properties for dye-sensitized solar cells

T2 - Dalton Transactions

AU - Lavrova, Maria A

AU - Mishurinskiy, Sergey A

AU - Smirnov, Daniil E.

AU - Kalle, Paulina

AU - Krivogina, Ekaterina V

AU - Kozyukhin, Sergey A.

AU - Emets, V. V.

AU - Emets, Viktor V

AU - Mariasina, Sofia S

AU - Dolzhenko, Vladimir D.

AU - Bezzubov, Stanislav I

PY - 2020

DA - 2020/10/28

PB - Royal Society of Chemistry (RSC)

SP - 16935-16945

IS - 46

VL - 49

PMID - 33188375

SN - 1477-9226

SN - 1477-9234

ER -

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@article{2020_Lavrova,

author = {Maria A Lavrova and Sergey A Mishurinskiy and Daniil E. Smirnov and Paulina Kalle and Ekaterina V Krivogina and Sergey A. Kozyukhin and V. V. Emets and Viktor V Emets and Sofia S Mariasina and Vladimir D. Dolzhenko and Stanislav I Bezzubov},

title = {Cyclometalated Ru(II) complexes with tunable redox and optical properties for dye-sensitized solar cells},

journal = {Dalton Transactions},

year = {2020},

volume = {49},

publisher = {Royal Society of Chemistry (RSC)},

month = {oct},

url = {https://xlink.rsc.org/?DOI=D0DT03564E},

number = {46},

pages = {16935--16945},

doi = {10.1039/D0DT03564E}

}

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Lavrova, Maria A., et al. “Cyclometalated Ru(II) complexes with tunable redox and optical properties for dye-sensitized solar cells.” Dalton Transactions, vol. 49, no. 46, Oct. 2020, pp. 16935-16945. https://xlink.rsc.org/?DOI=D0DT03564E.