Dalton Transactions, volume 50, issue 46, pages 16990-16999

Tetranuclear Cr–Ln ferrocenecarboxylate complexes with a defect-dicubane structure: synthesis, magnetism, and thermolysis

Pavel S Koroteev ¹

Zhanna V Dobrokhotova ¹

Andrey B. Ilyukhin ¹

Ekaterina Belova ^{1, 2}

Ekaterina V Belova ^{1, 2}

Alexey Yapryntsev ¹

Alexey D. Yapryntsev ¹

Mathieu Rouzières ³

Rodolphe Clerac ³

Nikolay N. Efimov ¹

Show full list: 10 authors

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N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, GSP-1, Leninsky prosp. 31, 119991 Moscow, Russian Federation |

Lomonosov Moscow State University, Department of Chemistry, GSP-1, Leninskie Gory 1/3, 119991 Moscow, Russian Federation |

Univ. Bordeaux, CNRS, Centre de Recherche Paul Pascal, UMR 5031, 33600 Pessac, France |

Publication type: Journal Article

Publication date: 2021-09-14

Royal Society of Chemistry (RSC)

Journal: Dalton Transactions

scimago Q1

SJR: 0.697

CiteScore: 6.6

Impact factor: 3.5

ISSN: 14779226, 14779234

DOI: 10.1039/D1DT02562G

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PubMed ID: 34612322

Inorganic Chemistry

Abstract

New Cr–Fe–Ln complexes with ferrocenecarboxylate and triethanolamine ligands are obtained. Tb, Dy and Ho complexes are SMMs, and Dy one has the anisotropy barrier of 75 K. Thermolysis of complexes leads to Cr_0.75Fe_1.25O₃ and LnCr_0.25Fe_0.75O₃ phases.

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Publisher

Royal Society of Chemistry (RSC)

Journal

Dalton Transactions

scimago Q1

SJR

0.697

CiteScore

6.6

Impact factor

3.5

ISSN

14779226 (Print)

14779234 (Electronic)

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Tetranuclear Cr–Ln ferrocenecarboxylate complexes with a defect-dicubane structure: synthesis, magnetism, and thermolysis

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