Organic and Biomolecular Chemistry, volume 10, issue 15, pages 2973
Copper-catalyzed C-alkylation of secondary alcohols and methyl ketones with alcohols employing the aerobic relay race methodology
Shiheng Liao
1
,
Kangkang Yu
1
,
Qiang Li
1
,
Haiwen Tian
1
,
Zhengping Zhang
1
,
Xiaochun Yu
1
,
Qing Xu
1
1
College of Chemistry and Materials Engineering, WenZhou University, Wenzhou, China
|
Publication type: Journal Article
Publication date: 2012-01-20
Journal:
Organic and Biomolecular Chemistry
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor: 3.2
ISSN: 14770520, 14770539
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
By employing aerobic oxidation to aldehydes as a more effective alcohol activation strategy, ligand-free copper catalysts were found to be superior catalysts than other metals in aerobic dehydrative β-alkylation of secondary alcohols and α-alkylation of methyl ketones using alcohols as the green alkylating reagents. Based on our mechanistic studies and also supported by the literature, we deduce that the newly-proposed relay race process rather than the conventional borrowing hydrogen-type mechanisms should be the most possible and a more rational mechanism for the aerobic C-alkylation reactions.
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2 publications, 1.83%
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2 publications, 1.83%
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1 publication, 0.92%
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1 publication, 0.92%
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1 publication, 0.92%
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1 publication, 0.92%
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1 publication, 0.92%
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1
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3
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5
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7
8
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Citations by publishers
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5
10
15
20
25
30
35
40
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Wiley
40 publications, 36.7%
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American Chemical Society (ACS)
23 publications, 21.1%
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Royal Society of Chemistry (RSC)
18 publications, 16.51%
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Elsevier
15 publications, 13.76%
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Springer Nature
7 publications, 6.42%
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Shanghai Institute of Organic Chemistry
2 publications, 1.83%
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Society of Synthetic Organic Chemistry
1 publication, 0.92%
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Thieme
1 publication, 0.92%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 0.92%
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5
10
15
20
25
30
35
40
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Liao S. et al. Copper-catalyzed C-alkylation of secondary alcohols and methyl ketones with alcohols employing the aerobic relay race methodology // Organic and Biomolecular Chemistry. 2012. Vol. 10. No. 15. p. 2973.
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Liao S., Yu K., Li Q., Tian H., Zhang Z., Yu X., Xu Q. Copper-catalyzed C-alkylation of secondary alcohols and methyl ketones with alcohols employing the aerobic relay race methodology // Organic and Biomolecular Chemistry. 2012. Vol. 10. No. 15. p. 2973.
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TY - JOUR
DO - 10.1039/c1ob06739g
UR - https://doi.org/10.1039/c1ob06739g
TI - Copper-catalyzed C-alkylation of secondary alcohols and methyl ketones with alcohols employing the aerobic relay race methodology
T2 - Organic and Biomolecular Chemistry
AU - Liao, Shiheng
AU - Yu, Kangkang
AU - Tian, Haiwen
AU - Zhang, Zhengping
AU - Li, Qiang
AU - Yu, Xiaochun
AU - Xu, Qing
PY - 2012
DA - 2012/01/20 00:00:00
PB - Royal Society of Chemistry (RSC)
SP - 2973
IS - 15
VL - 10
SN - 1477-0520
SN - 1477-0539
ER -
Cite this
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@article{2012_Liao,
author = {Shiheng Liao and Kangkang Yu and Haiwen Tian and Zhengping Zhang and Qiang Li and Xiaochun Yu and Qing Xu},
title = {Copper-catalyzed C-alkylation of secondary alcohols and methyl ketones with alcohols employing the aerobic relay race methodology},
journal = {Organic and Biomolecular Chemistry},
year = {2012},
volume = {10},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://doi.org/10.1039/c1ob06739g},
number = {15},
pages = {2973},
doi = {10.1039/c1ob06739g}
}
Cite this
MLA
Copy
Liao, Shiheng, et al. “Copper-catalyzed C-alkylation of secondary alcohols and methyl ketones with alcohols employing the aerobic relay race methodology.” Organic and Biomolecular Chemistry, vol. 10, no. 15, Jan. 2012, p. 2973. https://doi.org/10.1039/c1ob06739g.