Green Chemistry, volume 20, issue 9, pages 1962-1969
Mechanochemistry – a new powerful green approach to the direct synthesis of alkoxysilanes
Temnikov Maxim
1
,
Zhemchugov Pavel V
1
,
Chistovalov Sergey M
1
,
Katsoulis Dimitris
2
,
Muzafarov Aziz M.
1, 3
2
Dow Corning Corporation. A wholly owned subsidiary of The Dow Chemical Company, 2200 W. Salzburg Rd, Midland, Michigan 48686, USA
|
Publication type: Journal Article
Publication date: 2018-03-19
Journal:
Green Chemistry
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 9.8
ISSN: 14639262, 14639270
Environmental Chemistry
Pollution
Abstract
The present work shows a new one-stage mechanochemical method for the direct synthesis of alkoxysilanes by silicon mechanoactivation followed by a reaction with an alcohol. Alkoxysilanes were obtained with nearly complete silicon and alcohol conversion. This method allows for a considerable simplification of the traditional multistage process by eliminating three stages that include silicon and catalyst preparation, and adapts it to green chemistry requirements. Vibration milling removed the oxide film, and the mechanoactivation of the large silicon fraction (1000–2000 μm) occurs in the reactor working space. Abrasion of the reactor walls and grinding bodies made of brass results in a developed catalytic surface on silicon, as it has been proven by a set of physical analytical methods such as scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), powder X-ray diffraction (PXRD), and X-ray photoelectron spectroscopy (XPS).
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Citations by publishers
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1 publication, 4.55%
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1 publication, 4.55%
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1 publication, 4.55%
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Temnikov M. et al. Mechanochemistry – a new powerful green approach to the direct synthesis of alkoxysilanes // Green Chemistry. 2018. Vol. 20. No. 9. pp. 1962-1969.
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Temnikov M., Anisimov A. A., Zhemchugov P. V., Kholodkov D. N., Goloveshkin A. S., Naumkin A. V., Chistovalov S. M., Katsoulis D., Muzafarov A. M. Mechanochemistry – a new powerful green approach to the direct synthesis of alkoxysilanes // Green Chemistry. 2018. Vol. 20. No. 9. pp. 1962-1969.
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RIS
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TY - JOUR
DO - 10.1039/c7gc03862c
UR - https://doi.org/10.1039%2Fc7gc03862c
TI - Mechanochemistry – a new powerful green approach to the direct synthesis of alkoxysilanes
T2 - Green Chemistry
AU - Temnikov, Maxim
AU - Zhemchugov, Pavel V
AU - Kholodkov, Dmitry N
AU - Naumkin, Alexander V.
AU - Chistovalov, Sergey M
AU - Katsoulis, Dimitris
AU - Muzafarov, Aziz M.
AU - Anisimov, Anton A.
AU - Goloveshkin, Alexander S.
PY - 2018
DA - 2018/03/19 00:00:00
PB - Royal Society of Chemistry (RSC)
SP - 1962-1969
IS - 9
VL - 20
SN - 1463-9262
SN - 1463-9270
ER -
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BibTex
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@article{2018_Temnikov,
author = {Maxim Temnikov and Pavel V Zhemchugov and Dmitry N Kholodkov and Alexander V. Naumkin and Sergey M Chistovalov and Dimitris Katsoulis and Aziz M. Muzafarov and Anton A. Anisimov and Alexander S. Goloveshkin},
title = {Mechanochemistry – a new powerful green approach to the direct synthesis of alkoxysilanes},
journal = {Green Chemistry},
year = {2018},
volume = {20},
publisher = {Royal Society of Chemistry (RSC)},
month = {mar},
url = {https://doi.org/10.1039%2Fc7gc03862c},
number = {9},
pages = {1962--1969},
doi = {10.1039/c7gc03862c}
}
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MLA
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Temnikov, Maxim, et al. “Mechanochemistry – a new powerful green approach to the direct synthesis of alkoxysilanes.” Green Chemistry, vol. 20, no. 9, Mar. 2018, pp. 1962-1969. https://doi.org/10.1039%2Fc7gc03862c.