PdCl2(CH3CN)2-catalyzed regioselective C–H olefinations of 2-amino biaryls with vinylsilanes as unactivated alkenes
Qiao Ying Sun
1
,
Qiao-Ying Sun
1, 2, 3, 4, 5
,
Zhao Li
1
,
Xu Zheng
1
,
Xu Zheng
1, 2, 3, 4, 5
,
Zhan Jiang Zheng
1
,
Zhan-Jiang Zheng
1, 2, 3, 4, 5
,
Jian Cao
1, 2, 3, 4, 5
,
Ke Fang Yang
1
,
Ke-Fang Yang
1, 2, 3, 4, 5
,
Yu-Ming Cui
1, 2, 3, 4, 5
,
Liwen Xu
1, 2, 3, 4, 5
2
Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education
4
Hangzhou 311121
|
5
P. R. China
|
Publication type: Journal Article
Publication date: 2019-05-01
scimago Q1
wos Q2
SJR: 1.037
CiteScore: 7.4
Impact factor: 4.2
ISSN: 13597345, 1364548X
PubMed ID:
31086887
Materials Chemistry
Metals and Alloys
Surfaces, Coatings and Films
General Chemistry
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Catalysis
Abstract
The first example of palladium-catalyzed chelation-assisted C–H olefination of 2-amino biaryls using readily available vinylsilanes as unactivated olefinating reagents has been developed, affording valuable arylated vinylsilane compounds in moderate to excellent yields and with exclusive (E)-selectivities.
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Total citations:
21
Citations from 2024:
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(38.1%)
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GOST
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Sun Q. Y. et al. PdCl2(CH3CN)2-catalyzed regioselective C–H olefinations of 2-amino biaryls with vinylsilanes as unactivated alkenes // Chemical Communications. 2019. Vol. 55. No. 44. pp. 6229-6232.
GOST all authors (up to 50)
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Sun Q. Y., Sun Q., Li Z., Zheng X., Xu Zheng, Zheng Z. J., Zheng Z., Cao J., Yang K. F., Yang K., Cui Y., Xu L. PdCl2(CH3CN)2-catalyzed regioselective C–H olefinations of 2-amino biaryls with vinylsilanes as unactivated alkenes // Chemical Communications. 2019. Vol. 55. No. 44. pp. 6229-6232.
Cite this
RIS
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TY - JOUR
DO - 10.1039/c9cc02199j
UR - https://xlink.rsc.org/?DOI=C9CC02199J
TI - PdCl2(CH3CN)2-catalyzed regioselective C–H olefinations of 2-amino biaryls with vinylsilanes as unactivated alkenes
T2 - Chemical Communications
AU - Sun, Qiao Ying
AU - Sun, Qiao-Ying
AU - Li, Zhao
AU - Zheng, Xu
AU - Xu Zheng
AU - Zheng, Zhan Jiang
AU - Zheng, Zhan-Jiang
AU - Cao, Jian
AU - Yang, Ke Fang
AU - Yang, Ke-Fang
AU - Cui, Yu-Ming
AU - Xu, Liwen
PY - 2019
DA - 2019/05/01
PB - Royal Society of Chemistry (RSC)
SP - 6229-6232
IS - 44
VL - 55
PMID - 31086887
SN - 1359-7345
SN - 1364-548X
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2019_Sun,
author = {Qiao Ying Sun and Qiao-Ying Sun and Zhao Li and Xu Zheng and Xu Zheng and Zhan Jiang Zheng and Zhan-Jiang Zheng and Jian Cao and Ke Fang Yang and Ke-Fang Yang and Yu-Ming Cui and Liwen Xu},
title = {PdCl2(CH3CN)2-catalyzed regioselective C–H olefinations of 2-amino biaryls with vinylsilanes as unactivated alkenes},
journal = {Chemical Communications},
year = {2019},
volume = {55},
publisher = {Royal Society of Chemistry (RSC)},
month = {may},
url = {https://xlink.rsc.org/?DOI=C9CC02199J},
number = {44},
pages = {6229--6232},
doi = {10.1039/c9cc02199j}
}
Cite this
MLA
Copy
Sun, Qiao Ying, et al. “PdCl2(CH3CN)2-catalyzed regioselective C–H olefinations of 2-amino biaryls with vinylsilanes as unactivated alkenes.” Chemical Communications, vol. 55, no. 44, May. 2019, pp. 6229-6232. https://xlink.rsc.org/?DOI=C9CC02199J.