Nickel-catalyzed insertions of vinylidenes into Si–H bonds
Тип публикации: Journal Article
Дата публикации: 2020-10-27
SCImago Q1
WOS Q2
БС1
SJR: 0.907
CiteScore: 7.4
Impact factor: 4.2
ISSN: 13597345, 1364548X
PubMed ID:
33141128
Materials Chemistry
Metals and Alloys
Surfaces, Coatings and Films
General Chemistry
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Catalysis
Краткое описание
A nickel-catalyzed reductive cyclization of 1,1-dichloroalkenyl silanes is reported. The products of this reaction are unsaturated five- or six-membered silacycles. Intermolecular variants are also described, providing access to trisubstituted vinyl silanes that are not accessible by alkyne hydrosilylation or sila-Heck-type processes. A variety of silanes can be utilized, including those that serve as nucleophilic partners in Hiyama cross-coupling reactions. Mechanistic studies using deuterium-labelled silanes are described.
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ГОСТ
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Biswas S. et al. Nickel-catalyzed insertions of vinylidenes into Si–H bonds // Chemical Communications. 2020. Vol. 56. No. 91. pp. 14175-14178.
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Biswas S., Pal S., Uyeda C. Nickel-catalyzed insertions of vinylidenes into Si–H bonds // Chemical Communications. 2020. Vol. 56. No. 91. pp. 14175-14178.
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TY - JOUR
DO - 10.1039/d0cc05970f
UR - https://xlink.rsc.org/?DOI=D0CC05970F
TI - Nickel-catalyzed insertions of vinylidenes into Si–H bonds
T2 - Chemical Communications
AU - Biswas, Sourish
AU - Pal, Sudipta
AU - Uyeda, Christopher
PY - 2020
DA - 2020/10/27
PB - Royal Society of Chemistry (RSC)
SP - 14175-14178
IS - 91
VL - 56
PMID - 33141128
SN - 1359-7345
SN - 1364-548X
ER -
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BibTex (до 50 авторов)
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@article{2020_Biswas,
author = {Sourish Biswas and Sudipta Pal and Christopher Uyeda},
title = {Nickel-catalyzed insertions of vinylidenes into Si–H bonds},
journal = {Chemical Communications},
year = {2020},
volume = {56},
publisher = {Royal Society of Chemistry (RSC)},
month = {oct},
url = {https://xlink.rsc.org/?DOI=D0CC05970F},
number = {91},
pages = {14175--14178},
doi = {10.1039/d0cc05970f}
}
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MLA
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Biswas, Sourish, et al. “Nickel-catalyzed insertions of vinylidenes into Si–H bonds.” Chemical Communications, vol. 56, no. 91, Oct. 2020, pp. 14175-14178. https://xlink.rsc.org/?DOI=D0CC05970F.
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