Organic Chemistry Frontiers

, volume 7 , issue 13 , pages 1717-1742

Cross-dehydrogenative coupling involving benzylic and allylic C–H bonds

Irene Bosque ^{1, 2, 3, 4, 5, 6}

Rafael Chinchilla ^{1, 2, 3, 4, 5, 6}

José Carlos González-Gómez ^{1, 2, 3, 4, 5, 6}

David Guijarro ^{1, 2, 3, 4, 5, 6}

FJ Alonso ^{1, 2, 3, 4, 5, 6}

Hide authors affiliations Show authors affiliations: 6 affiliations

Instituto de Síntesis Orgánica and Departamento de Química Orgánica, Facultad de Ciencias, Universidad de Alicante, Apdo. 99, 03080 Alicante, Spain |

Instituto de Síntesis Orgánica and Departamento de Química Orgánica

Facultad de Ciencias

⁴

Universidad de Alicante |

⁵

03080 Alicante |

⁶

SPAIN |

Publication type: Journal Article

Publication date: 2020-05-26

Royal Society of Chemistry (RSC)

Organic Chemistry Frontiers

scimago Q1

wos Q1

SJR: 1.068

CiteScore: 8.2

Impact factor: 4.7

ISSN: 20524110, 20524129

DOI: 10.1039/d0qo00587h

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Organic Chemistry

Abstract

In recent years, the cross-dehydrogenative coupling (CDC) has demonstrated to be a powerful synthetic tool to form C–C bonds from two C–H bonds. This high atom-economic transformation is an attractive alternative to the classical substitution and coupling approaches for the benzylation and allylation of carbon centers, which rely on the reaction of adequately functionalized starting materials. This review emphasizes the utility of the CDC through the coupling of benzylic and allylic C–H bonds with C(sp)–H, C(sp2)–H and C(sp3)–H bonds.

Found

1 citation

Budnikova Yulia

DSc in Chemistry, professor

259 publications, 4 512 citations, 54 reviews

h-index: 34

A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences

Kazan Scientific Center of the Russian Academy of Sciences

Research interests

C-H functionalization

Catalysis

Charge transfer

Chemistry of organoelement compounds

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GOST |

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GOST Copy

Bosque I. et al. Cross-dehydrogenative coupling involving benzylic and allylic C–H bonds // Organic Chemistry Frontiers. 2020. Vol. 7. No. 13. pp. 1717-1742.

GOST all authors (up to 50) Copy

Bosque I., Chinchilla R., González-Gómez J. C., Guijarro D., Alonso F. Cross-dehydrogenative coupling involving benzylic and allylic C–H bonds // Organic Chemistry Frontiers. 2020. Vol. 7. No. 13. pp. 1717-1742.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1039/d0qo00587h

UR - https://xlink.rsc.org/?DOI=D0QO00587H

TI - Cross-dehydrogenative coupling involving benzylic and allylic C–H bonds

T2 - Organic Chemistry Frontiers

AU - Bosque, Irene

AU - Chinchilla, Rafael

AU - González-Gómez, José Carlos

AU - Guijarro, David

AU - Alonso, FJ

PY - 2020

DA - 2020/05/26

PB - Royal Society of Chemistry (RSC)

SP - 1717-1742

IS - 13

VL - 7

SN - 2052-4110

SN - 2052-4129

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2020_Bosque,

author = {Irene Bosque and Rafael Chinchilla and José Carlos González-Gómez and David Guijarro and FJ Alonso},

title = {Cross-dehydrogenative coupling involving benzylic and allylic C–H bonds},

journal = {Organic Chemistry Frontiers},

year = {2020},

volume = {7},

publisher = {Royal Society of Chemistry (RSC)},

month = {may},

url = {https://xlink.rsc.org/?DOI=D0QO00587H},

number = {13},

pages = {1717--1742},

doi = {10.1039/d0qo00587h}

}

MLA

Cite this

MLA Copy

Bosque, Irene, et al. “Cross-dehydrogenative coupling involving benzylic and allylic C–H bonds.” Organic Chemistry Frontiers, vol. 7, no. 13, May. 2020, pp. 1717-1742. https://xlink.rsc.org/?DOI=D0QO00587H.

Publisher

Royal Society of Chemistry (RSC)

Journal

Organic Chemistry Frontiers

scimago Q1

wos Q1

SJR

1.068

CiteScore

8.2

Impact factor

4.7

ISSN

20524110 (Print)

20524129 (Electronic)

Profiles

Jose C Gonzalez-Gomez