A comprehensive review of caged phosphines: synthesis, catalytic applications, and future perspectives
Harshita Shet
1, 2, 3, 4, 5, 6, 7
,
Udaysinh Parmar
6, 8, 9, 10
,
Shatrughn Bhilare
1
,
Anant R. Kapdi
1, 3, 4, 5, 6
1
Department of Chemistry, Institute of Chemical Technology, Nathalal Parekh road, Matunga, Mumbai 400019, India
|
3
DEPARTMENT OF CHEMISTRY
4
Institute of Chemical Technology
5
Mumbai 400019
|
6
INDIA
|
7
Institute of Chemical Technology-Indian Oil Odisha Campus
8
Aether Industries Limited, Road No. 3, Hojiwala Industrial Estate, Sachin, Surat 394230, India
|
9
Aether Industries Limited
10
Surat 394230
|
Publication type: Journal Article
Publication date: 2021-01-01
scimago Q1
wos Q1
SJR: 1.068
CiteScore: 8.2
Impact factor: 4.7
ISSN: 20524110, 20524129
Organic Chemistry
Abstract
Phosphines have played an important role in the rapid rise of transition metal-catalysed processes and with the possibility of fine-tuning the electronic and steric properties of these ligands, several synthesis challenges have been overcome in the past decades leading to their application in academia and industry. Caged phosphines are one such class of phosphines with the phosphorus atom at the bridgehead of a cyclic cage and have exhibited excellent control of the steric and electronic properties leading to their applications as ligands in a vast number of catalytic processes. This review provides an overview of the origin of this area of research, as well as the developments that have taken place and how the unique properties of these ligand systems could help to fine-tune the reactivity. A critical analysis of the area reveals some lacunae that will also be highlighted to promote further developments in this area of research.
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37
Total citations:
37
Citations from 2024:
11
(30.56%)
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GOST
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Shet H. et al. A comprehensive review of caged phosphines: synthesis, catalytic applications, and future perspectives // Organic Chemistry Frontiers. 2021. Vol. 8. No. 7. pp. 1599-1656.
GOST all authors (up to 50)
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Shet H., Parmar U., Bhilare S., Kapdi A. R. A comprehensive review of caged phosphines: synthesis, catalytic applications, and future perspectives // Organic Chemistry Frontiers. 2021. Vol. 8. No. 7. pp. 1599-1656.
Cite this
RIS
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TY - JOUR
DO - 10.1039/d0qo01194k
UR - https://xlink.rsc.org/?DOI=D0QO01194K
TI - A comprehensive review of caged phosphines: synthesis, catalytic applications, and future perspectives
T2 - Organic Chemistry Frontiers
AU - Shet, Harshita
AU - Parmar, Udaysinh
AU - Bhilare, Shatrughn
AU - Kapdi, Anant R.
PY - 2021
DA - 2021/01/01
PB - Royal Society of Chemistry (RSC)
SP - 1599-1656
IS - 7
VL - 8
SN - 2052-4110
SN - 2052-4129
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2021_Shet,
author = {Harshita Shet and Udaysinh Parmar and Shatrughn Bhilare and Anant R. Kapdi},
title = {A comprehensive review of caged phosphines: synthesis, catalytic applications, and future perspectives},
journal = {Organic Chemistry Frontiers},
year = {2021},
volume = {8},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://xlink.rsc.org/?DOI=D0QO01194K},
number = {7},
pages = {1599--1656},
doi = {10.1039/d0qo01194k}
}
Cite this
MLA
Copy
Shet, Harshita, et al. “A comprehensive review of caged phosphines: synthesis, catalytic applications, and future perspectives.” Organic Chemistry Frontiers, vol. 8, no. 7, Jan. 2021, pp. 1599-1656. https://xlink.rsc.org/?DOI=D0QO01194K.