Royal Society of Chemistry (RSC)
Organic and Biomolecular Chemistry
,  volume 19 ,  issue 47 ,  pages 10332-10336

Cobalt(iii)-catalyzed C–H amidation of N,N-dialkyl thiobenzamides by sulfur coordination

Publication type: Journal Article
Publication date: 2021-11-18
Royal Society of Chemistry (RSC)
scimago Q2
wos Q2
SJR: 0.600
CiteScore: 5.2
Impact factor: 2.7
ISSN: 14770520, 14770539
DOI:  10.1039/d1ob02034j
PubMed ID:  34817486
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
An efficient inexpensive cobalt(III)-catalyzed intermolecular amidation of N,N-dialkyl thiobenzamides with 1,4,2-dioxazol-5-ones via C-H bond activation is described. The reaction proceeds with high functional group tolerance under external oxidant free conditions, providing a straightforward approach for the direct modification of thioamide derivatives, which are prevalent organic motifs found in vital biological and pharmaceutical molecules.
Found 
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GOST |
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GOST Copy
Gao P. et al. Cobalt(iii)-catalyzed C–H amidation of N,N-dialkyl thiobenzamides by sulfur coordination // Organic and Biomolecular Chemistry. 2021. Vol. 19. No. 47. pp. 10332-10336.
GOST all authors (up to 50) Copy
Gao P., Zhang X., Zheng Q. Z. Cobalt(iii)-catalyzed C–H amidation of N,N-dialkyl thiobenzamides by sulfur coordination // Organic and Biomolecular Chemistry. 2021. Vol. 19. No. 47. pp. 10332-10336.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1039/d1ob02034j
UR - https://xlink.rsc.org/?DOI=D1OB02034J
TI - Cobalt(iii)-catalyzed C–H amidation of N,N-dialkyl thiobenzamides by sulfur coordination
T2 - Organic and Biomolecular Chemistry
AU - Gao, Pengpeng
AU - Zhang, Xiaohui
AU - Zheng, Qing Zhong
PY - 2021
DA - 2021/11/18
PB - Royal Society of Chemistry (RSC)
SP - 10332-10336
IS - 47
VL - 19
PMID - 34817486
SN - 1477-0520
SN - 1477-0539
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2021_Gao,
author = {Pengpeng Gao and Xiaohui Zhang and Qing Zhong Zheng},
title = {Cobalt(iii)-catalyzed C–H amidation of N,N-dialkyl thiobenzamides by sulfur coordination},
journal = {Organic and Biomolecular Chemistry},
year = {2021},
volume = {19},
publisher = {Royal Society of Chemistry (RSC)},
month = {nov},
url = {https://xlink.rsc.org/?DOI=D1OB02034J},
number = {47},
pages = {10332--10336},
doi = {10.1039/d1ob02034j}
}
MLA
Cite this
MLA Copy
Gao, Pengpeng, et al. “Cobalt(iii)-catalyzed C–H amidation of N,N-dialkyl thiobenzamides by sulfur coordination.” Organic and Biomolecular Chemistry, vol. 19, no. 47, Nov. 2021, pp. 10332-10336. https://xlink.rsc.org/?DOI=D1OB02034J.