Open Access
Fluorinated Iron(ii ) clathrochelate units in metalorganic based copolymers: improved porosity, iodine uptake, and dye adsorption properties
Suchetha Shetty
1, 2, 3, 4, 5
,
Noorullah Baig
1, 2, 3, 4, 5
,
Atikur Hassan
6, 7, 8, 9, 10
,
Saleh Al-Mousawi
3, 6, 11
,
Neeladri Das
6, 7, 8, 9, 10
,
Bassam Alameddine
1, 2, 3, 4, 5
1
Department of Mathematics and Natural Sciences
3
Kuwait
|
4
Functional Materials Group – CAMB
5
GUST
6
DEPARTMENT OF CHEMISTRY
8
Patna 801106
|
9
INDIA
|
Publication type: Journal Article
Publication date: 2021-04-22
scimago Q1
wos Q2
SJR: 0.777
CiteScore: 7.6
Impact factor: 4.6
ISSN: 20462069
PubMed ID:
35424059
General Chemistry
General Chemical Engineering
Abstract
We report the synthesis of metalorganic copolymers made from the palladium catalyzed Sonogashira cross-coupling reaction between various iron(ii) clathrochelate building blocks with diethynyl-triptycene and fluorene derivatives. The target copolymers CCP1-5 were isolated in excellent yield and characterized by various instrumental analysis techniques. Interestingly, investigation of the copolymers' porosity properties discloses BET surface areas up to 337 m2 g-1 for the target compounds bearing fluorinated iron(ii) clathrochelate units CCP2,5. Moreover, the fluorinated copolymers display an outstanding uptake capacity of iodine with a maximum adsorption of 200 wt%. The target metalorganic copolymers CCP1-5 reveal very good adsorption of organic dyes, namely, methyl blue and methylene blue, from aqueous media.
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29
Total citations:
29
Citations from 2024:
12
(41.37%)
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GOST
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Shetty S. et al. Fluorinated Iron(ii) clathrochelate units in metalorganic based copolymers: improved porosity, iodine uptake, and dye adsorption properties // RSC Advances. 2021. Vol. 11. No. 25. pp. 14986-14995.
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Shetty S., Baig N., Hassan A., Al-Mousawi S., Das N., Alameddine B. Fluorinated Iron(ii) clathrochelate units in metalorganic based copolymers: improved porosity, iodine uptake, and dye adsorption properties // RSC Advances. 2021. Vol. 11. No. 25. pp. 14986-14995.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1039/d1ra02357h
UR - https://xlink.rsc.org/?DOI=D1RA02357H
TI - Fluorinated Iron(ii) clathrochelate units in metalorganic based copolymers: improved porosity, iodine uptake, and dye adsorption properties
T2 - RSC Advances
AU - Shetty, Suchetha
AU - Baig, Noorullah
AU - Hassan, Atikur
AU - Al-Mousawi, Saleh
AU - Das, Neeladri
AU - Alameddine, Bassam
PY - 2021
DA - 2021/04/22
PB - Royal Society of Chemistry (RSC)
SP - 14986-14995
IS - 25
VL - 11
PMID - 35424059
SN - 2046-2069
ER -
Cite this
BibTex (up to 50 authors)
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@article{2021_Shetty,
author = {Suchetha Shetty and Noorullah Baig and Atikur Hassan and Saleh Al-Mousawi and Neeladri Das and Bassam Alameddine},
title = {Fluorinated Iron(ii) clathrochelate units in metalorganic based copolymers: improved porosity, iodine uptake, and dye adsorption properties},
journal = {RSC Advances},
year = {2021},
volume = {11},
publisher = {Royal Society of Chemistry (RSC)},
month = {apr},
url = {https://xlink.rsc.org/?DOI=D1RA02357H},
number = {25},
pages = {14986--14995},
doi = {10.1039/d1ra02357h}
}
Cite this
MLA
Copy
Shetty, Suchetha, et al. “Fluorinated Iron(ii) clathrochelate units in metalorganic based copolymers: improved porosity, iodine uptake, and dye adsorption properties.” RSC Advances, vol. 11, no. 25, Apr. 2021, pp. 14986-14995. https://xlink.rsc.org/?DOI=D1RA02357H.