Soft Matter, volume 18, issue 12, pages 2441-2451
New types of hyperbranched 1,2,3-triazole-alkoxysiloxane functional polymers for metal embedded nanocomposite surface coatings
Migulin Dmitry A
1
,
Rozanova Julia V
1
,
Migulin Vasily A
2
,
Cherkaev Georgy V
1
,
Meshkov Ivan B
1
,
Zezin Alexey A
1, 3
,
Muzafarov Aziz M.
1
Publication type: Journal Article
Publication date: 2022-02-23
Journal:
Soft Matter
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor: 3.4
ISSN: 1744683X, 17446848
General Chemistry
Condensed Matter Physics
Abstract
In this study, using the "click-chemistry" azide-alkyne cycloaddition reaction, two new types of polymers, namely, water-soluble amine-functional and water-insoluble pyridine-functional hyperbranched 1,2,3-triazoleorganoethoxysiloxane polymers, capable of stabilizing ultra-small silver nanoparticles and efficient for chemical surface modification were synthesized and characterized by 1H-NMR, 13C-NMR, 29Si-NMR and FT-IR spectroscopy, MALDI and GPC. Coordinatively active hetero-organic polymers with a flexible branched polyethoxysiloxane backbone bearing chelating 1,2,3-triazolyl-dimethylamine and -pyridine conjugated functional groups were exploited towards coordination with Ag+ metal ions, and formation and stabilization of narrowly dispersed silver nanoparticles (Ag-NPs) obtained in the process of radiation induced metal ion reduction. The influence of the chemically assisted radiation process on the Ag-NP size and size distribution was investigated. Hyperbranched polyorganoethoxysiloxanes loaded with Ag-NPs were covalently cross-linked on a Stöber silica surface, demonstrating the efficiency of the developed hetero-organic functional polymers in the preparation of functional nanocomposite coatings for various applications (heterogeneous catalytic systems, antibacterial materials, nanoparticle-based optical sensing devices, etc.). The nanocomposites were investigated and characterized by TEM-EDS, DLS, UV-Vis spectroscopy and 29Si MAS NMR spectroscopy.
Citations by journals
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1
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Polymer Chemistry
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Polymer Chemistry
1 publication, 33.33%
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Pharmaceutics
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1 publication, 33.33%
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ChemistrySelect
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ChemistrySelect
1 publication, 33.33%
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1
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Citations by publishers
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1
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Royal Society of Chemistry (RSC)
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Royal Society of Chemistry (RSC)
1 publication, 33.33%
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Multidisciplinary Digital Publishing Institute (MDPI)
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Multidisciplinary Digital Publishing Institute (MDPI)
1 publication, 33.33%
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Wiley
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Wiley
1 publication, 33.33%
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1
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- Statistics recalculated weekly.
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Migulin D. A. et al. New types of hyperbranched 1,2,3-triazole-alkoxysiloxane functional polymers for metal embedded nanocomposite surface coatings // Soft Matter. 2022. Vol. 18. No. 12. pp. 2441-2451.
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Migulin D. A., Rozanova J. V., Migulin V. A., Cherkaev G. V., Meshkov I. B., Zezin A. A., Muzafarov A. M. New types of hyperbranched 1,2,3-triazole-alkoxysiloxane functional polymers for metal embedded nanocomposite surface coatings // Soft Matter. 2022. Vol. 18. No. 12. pp. 2441-2451.
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TY - JOUR
DO - 10.1039/d1sm01801a
UR - https://doi.org/10.1039%2Fd1sm01801a
TI - New types of hyperbranched 1,2,3-triazole-alkoxysiloxane functional polymers for metal embedded nanocomposite surface coatings
T2 - Soft Matter
AU - Migulin, Dmitry A
AU - Rozanova, Julia V
AU - Migulin, Vasily A
AU - Cherkaev, Georgy V
AU - Meshkov, Ivan B
AU - Zezin, Alexey A
AU - Muzafarov, Aziz M.
PY - 2022
DA - 2022/02/23 00:00:00
PB - Royal Society of Chemistry (RSC)
SP - 2441-2451
IS - 12
VL - 18
SN - 1744-683X
SN - 1744-6848
ER -
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@article{2022_Migulin,
author = {Dmitry A Migulin and Julia V Rozanova and Vasily A Migulin and Georgy V Cherkaev and Ivan B Meshkov and Alexey A Zezin and Aziz M. Muzafarov},
title = {New types of hyperbranched 1,2,3-triazole-alkoxysiloxane functional polymers for metal embedded nanocomposite surface coatings},
journal = {Soft Matter},
year = {2022},
volume = {18},
publisher = {Royal Society of Chemistry (RSC)},
month = {feb},
url = {https://doi.org/10.1039%2Fd1sm01801a},
number = {12},
pages = {2441--2451},
doi = {10.1039/d1sm01801a}
}
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MLA
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Migulin, Dmitry A., et al. “New types of hyperbranched 1,2,3-triazole-alkoxysiloxane functional polymers for metal embedded nanocomposite surface coatings.” Soft Matter, vol. 18, no. 12, Feb. 2022, pp. 2441-2451. https://doi.org/10.1039%2Fd1sm01801a.