Chemical Communications, volume 58, issue 81, pages 11386-11389

Silicon–nitrogen bond formation via dealkynative coupling of amines with bis(trimethylsilyl)acetylene mediated by KHMDS

Krzysztof Kucinski ¹

Grzegorz Hreczycho ¹

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Faculty of Chemistry, Adam Mickiewicz University in Poznań, Ul. Uniwersytetu Poznańskiego 8, 61-614 Poznań, Poland |

Publication type: Journal Article

Publication date: 2022-09-13

Royal Society of Chemistry (RSC)

Journal: Chemical Communications

scimago Q1

SJR: 1.133

CiteScore: 8.6

Impact factor: 4.3

ISSN: 13597345, 1364548X

DOI: 10.1039/d2cc04413g

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Materials Chemistry

Metals and Alloys

Surfaces, Coatings and Films

General Chemistry

Ceramics and Composites

Electronic, Optical and Magnetic Materials

Catalysis

Abstract

The catalytic synthesis of silylamines mediated by s- and p-block catalysts is largely underdeveloped. Herein, commercially available potassium bis(trimethylsilyl)amide serves as an efficient alternative to transition metal complexes. N-H/Si-C dealkynative coupling was achieved by means of user-friendly main-group catalysis with ample substrate scope and high chemoselectivity.

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Publisher

Royal Society of Chemistry (RSC)

Journal

Chemical Communications

scimago Q1

SJR

1.133

CiteScore

8.6

Impact factor

4.3

ISSN

13597345 (Print)

1364548X (Electronic)

Silicon–nitrogen bond formation via dealkynative coupling of amines with bis(trimethylsilyl)acetylene mediated by KHMDS

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