Studies on the effect of polyhedral carboranes on the physicochemical properties of polycarboranosiloxanes
E O Minyaylo
1, 2
,
V. Yu. Zubova
1, 3
,
A V Zaitsev
1
,
G G Nikiforova
1
,
M I Buzin
1
,
Anton A. Anisimov
1, 2
,
A M Muzafarov
1, 4
Publication type: Journal Article
Publication date: 2023-03-03
scimago Q1
wos Q2
SJR: 0.842
CiteScore: 7.6
Impact factor: 3.9
ISSN: 17599954, 17599962
Organic Chemistry
Biochemistry
Polymers and Plastics
Bioengineering
Abstract
In this work, polycarboranosiloxanes (Mn = 25.5–31.3 kDa) with well-defined structures and a varying content of the carborane moiety (2–15 wt%) were obtained. TGA and DSC methods were used to study their thermal properties and the rheological behavior of melts was studied. It was found that as the content of carboranes in the structure of these polymers exceeds 9 wt%, the crystallization of the siloxane chain is suppressed. Data of rheological studies indicate that phase separation occurs in such hybrid carboranosiloxane systems.
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Minyaylo E. O. et al. Studies on the effect of polyhedral carboranes on the physicochemical properties of polycarboranosiloxanes // Polymer Chemistry. 2023. Vol. 14. No. 13. pp. 1514-1525.
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Minyaylo E. O., Zubova V. Y., Zaitsev A. V., Ol'shevskaya V. A., Nikiforova G. G., Buzin M. I., Anisimov A. A., Muzafarov A. M. Studies on the effect of polyhedral carboranes on the physicochemical properties of polycarboranosiloxanes // Polymer Chemistry. 2023. Vol. 14. No. 13. pp. 1514-1525.
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TY - JOUR
DO - 10.1039/d2py01539k
UR - https://xlink.rsc.org/?DOI=D2PY01539K
TI - Studies on the effect of polyhedral carboranes on the physicochemical properties of polycarboranosiloxanes
T2 - Polymer Chemistry
AU - Minyaylo, E O
AU - Zubova, V. Yu.
AU - Zaitsev, A V
AU - Ol'shevskaya, Valentina A.
AU - Nikiforova, G G
AU - Buzin, M I
AU - Anisimov, Anton A.
AU - Muzafarov, A M
PY - 2023
DA - 2023/03/03
PB - Royal Society of Chemistry (RSC)
SP - 1514-1525
IS - 13
VL - 14
SN - 1759-9954
SN - 1759-9962
ER -
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@article{2023_Minyaylo,
author = {E O Minyaylo and V. Yu. Zubova and A V Zaitsev and Valentina A. Ol'shevskaya and G G Nikiforova and M I Buzin and Anton A. Anisimov and A M Muzafarov},
title = {Studies on the effect of polyhedral carboranes on the physicochemical properties of polycarboranosiloxanes},
journal = {Polymer Chemistry},
year = {2023},
volume = {14},
publisher = {Royal Society of Chemistry (RSC)},
month = {mar},
url = {https://xlink.rsc.org/?DOI=D2PY01539K},
number = {13},
pages = {1514--1525},
doi = {10.1039/d2py01539k}
}
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MLA
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Minyaylo, E. O., et al. “Studies on the effect of polyhedral carboranes on the physicochemical properties of polycarboranosiloxanes.” Polymer Chemistry, vol. 14, no. 13, Mar. 2023, pp. 1514-1525. https://xlink.rsc.org/?DOI=D2PY01539K.