Open Access
RSC Advances, volume 12, issue 44, pages 28490-28493
[3+2] click chemistry approach to tetrazine containing polymers
David E. Chavez
1
,
Bryce Tappan
1
,
Valerie A Kuehl
1
,
Andrew M Schmalzer
1
,
Philip W. Leonard
1
,
Ruilian Wu
1
,
Gregory H Imler
2
,
Damon A. Parrish
2
Publication type: Journal Article
Publication date: 2022-10-06
PubMed ID:
36320529
General Chemistry
General Chemical Engineering
Abstract
We report a [3+2] cycloaddition using 3,6-bis-propargyloxy-1,2,4,5-tetrazine and azides to synthesize energetic polymers containing 1,2,4,5-tetrazine within the scaffold. This work also includes [3+2] cycloaddition to crosslink azide containing glycidyl azide polymer (GAP). These reactions provide pathways for incorporation of 1,2,4,5-tetrazine into novel energetic materials using click-chemistry and provide an alternative polymer curing approach.
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