Reaction Chemistry and Engineering, volume 8, issue 5, pages 1005-1014
Sequential hydrothiolation-hydrosilylation: a route to the creation of new organosilicon compounds with preset structures
Krizhanovskiy Ilya
1, 2
,
Temnikov Maxim
1, 2
,
Drozdov Fedor
2, 3
,
Peregudov Alexander
1
,
Anisimov Anton A.
1, 2
Publication type: Journal Article
Publication date: 2023-01-05
Journal:
Reaction Chemistry and Engineering
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor: 3.9
ISSN: 20589883
Catalysis
Chemistry (miscellaneous)
Process Chemistry and Technology
Chemical Engineering (miscellaneous)
Fluid Flow and Transfer Processes
Abstract
An efficient approach to the preparation of functional organosilicon compounds by sequential hydrothiolation (Ht) and hydrosilylation (Hs) reactions using commercially available catalysts (Karstedt's catalyst) and activators (UV alone or UV in the presence of benzophenone) is presented. Structure–reactivity relationships for Si–H containing silanes with the sulfide bond in different positions (α, β, and γ, and via a siloxane spacer) were firstly demonstrated. This approach has been tested on disiloxane and then successfully applied for the modification of a cis-stereoregular silsesquioxane ring containing 4 vinyl and 4 hydrido groups. Also we demonstrated the efficiency of introducing alkoxy groups into a vinyl–hydride-containing disiloxane at both the Ht and Hs stages. Thus, the approach that we developed is a convenient and promising tool for the synthesis of complex organosilicon molecular ensembles with an unlimited variety of structures and substituents.
Citations by journals
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1
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Polymer Science - Series B
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Polymer Science - Series B
1 publication, 100%
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1
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Citations by publishers
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1
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Pleiades Publishing
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Pleiades Publishing
1 publication, 100%
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1
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Krizhanovskiy I. et al. Sequential hydrothiolation-hydrosilylation: a route to the creation of new organosilicon compounds with preset structures // Reaction Chemistry and Engineering. 2023. Vol. 8. No. 5. pp. 1005-1014.
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Krizhanovskiy I., Temnikov M., Drozdov F., Peregudov A., Anisimov A. A. Sequential hydrothiolation-hydrosilylation: a route to the creation of new organosilicon compounds with preset structures // Reaction Chemistry and Engineering. 2023. Vol. 8. No. 5. pp. 1005-1014.
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TY - JOUR
DO - 10.1039/d2re00420h
UR - https://doi.org/10.1039%2Fd2re00420h
TI - Sequential hydrothiolation-hydrosilylation: a route to the creation of new organosilicon compounds with preset structures
T2 - Reaction Chemistry and Engineering
AU - Krizhanovskiy, Ilya
AU - Temnikov, Maxim
AU - Drozdov, Fedor
AU - Peregudov, Alexander
AU - Anisimov, Anton A.
PY - 2023
DA - 2023/01/05 00:00:00
PB - Royal Society of Chemistry (RSC)
SP - 1005-1014
IS - 5
VL - 8
SN - 2058-9883
ER -
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@article{2023_Krizhanovskiy,
author = {Ilya Krizhanovskiy and Maxim Temnikov and Fedor Drozdov and Alexander Peregudov and Anton A. Anisimov},
title = {Sequential hydrothiolation-hydrosilylation: a route to the creation of new organosilicon compounds with preset structures},
journal = {Reaction Chemistry and Engineering},
year = {2023},
volume = {8},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://doi.org/10.1039%2Fd2re00420h},
number = {5},
pages = {1005--1014},
doi = {10.1039/d2re00420h}
}
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MLA
Copy
Krizhanovskiy, Ilya, et al. “Sequential hydrothiolation-hydrosilylation: a route to the creation of new organosilicon compounds with preset structures.” Reaction Chemistry and Engineering, vol. 8, no. 5, Jan. 2023, pp. 1005-1014. https://doi.org/10.1039%2Fd2re00420h.