Chemical Communications, volume 59, issue 28, pages 4173-4176

Hetero-Carbolong Chemistry: Experimental and Theoretical Studies of Diaza-Metallapentalenes

Publication type: Journal Article
Publication date: 2023-03-14
scimago Q1
SJR: 1.133
CiteScore: 8.6
Impact factor: 4.3
ISSN: 13597345, 1364548X
DOI:  10.1039/d3cc00029j
PubMed ID:  36939834
Materials Chemistry
Metals and Alloys
Surfaces, Coatings and Films
General Chemistry
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Catalysis
Abstract

Four diaza-osmapentalenes were prepared by two-step reactions, through treatment of an alkyne-coordinated osmium complex with azo compounds, followed by the addition of AgSbF6/CO. Their aromaticity was confirmed by crystal parameters,...

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