Dalton Transactions, volume 52, issue 25, pages 8728-8736

C2-Symmetric Atropisomeric N-Heterocyclic Carbene-Palladium(II) Complexes: Synthesis, Chiral Resolution and Application in enantioselective α-Arylation of Amides

Lingyu Kong 1
, 
Yajie Chou 1
, 
Muriel Albalat 1
, 
Marion Jean 1
, 
Nicolas Vanthuyne 1
, 
Stéphane Humbel 1
, 
Paola Nava 1
, 
HERVÉ CLAVIER 1
1
 
Publication type: Journal Article
Publication date: 2023-05-22
scimago Q1
SJR: 0.697
CiteScore: 6.6
Impact factor: 3.5
ISSN: 14779226, 14779234
DOI:  10.1039/d3dt01182h
PubMed ID:  37313746
Inorganic Chemistry
Abstract

The concept of atropisomeric N-heterocyclic carbene (NHC)-metal complexes was extended to NHCs possessing a C2-symmetry and implemented to prepare of palladium-based complexes. An in-depth study of the NHC precursors and...

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