том 14 издание 28 страницы 3262-3269

Anthraquinone-based oxime ester as visible-light photoinitiator for 3D photoprinting applications

Тип публикацииJournal Article
Дата публикации2023-06-27
scimago Q1
wos Q2
БС1
SJR0.842
CiteScore7.6
Impact factor3.9
ISSN17599954, 17599962
Organic Chemistry
Biochemistry
Polymers and Plastics
Bioengineering
Краткое описание
A novel anthraquinone-based oxime ester system (AQ-Ox) was successfully synthesized and used as a Type I visible-light photoinitiating system. The introduction of an anthraquinone moiety to the oxime ester group makes this system suitable for promoting photopolymerization under visible-light irradiation (LEDs@385, 405 and 455 nm) and allowed us to obtain high final acrylate conversions under laminate and air conditions in the free-radical polymerization (FRP) of an acrylate bio-based monomer. AQ-Ox also demonstrated better photoinitiating properties than commonly used Type I photoinitiators i.e. 2,2-dimethoxy-2-phenylacetophenone (DMPA) and phenylbis(2,4,6-trimethylbenzoyl)phosphine oxide (BAPO), and allowed the design of 3D objects by 3D photoprinting technology. This is the first example of an anthraquinone based oxime-ester used as a Type I photoinitiator for FRP at λ > 405 nm and under air.
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ГОСТ |
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Elian C. et al. Anthraquinone-based oxime ester as visible-light photoinitiator for 3D photoprinting applications // Polymer Chemistry. 2023. Vol. 14. No. 28. pp. 3262-3269.
ГОСТ со всеми авторами (до 50) Скопировать
Elian C., Sanosa N., Bogliotti N., Herrero C., Sampedro D., Versace D. L. Anthraquinone-based oxime ester as visible-light photoinitiator for 3D photoprinting applications // Polymer Chemistry. 2023. Vol. 14. No. 28. pp. 3262-3269.
RIS |
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TY - JOUR
DO - 10.1039/d3py00681f
UR - https://xlink.rsc.org/?DOI=D3PY00681F
TI - Anthraquinone-based oxime ester as visible-light photoinitiator for 3D photoprinting applications
T2 - Polymer Chemistry
AU - Elian, Christine
AU - Sanosa, Nil
AU - Bogliotti, N
AU - Herrero, Christian
AU - Sampedro, Diego
AU - Versace, D L
PY - 2023
DA - 2023/06/27
PB - Royal Society of Chemistry (RSC)
SP - 3262-3269
IS - 28
VL - 14
SN - 1759-9954
SN - 1759-9962
ER -
BibTex |
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BibTex (до 50 авторов) Скопировать
@article{2023_Elian,
author = {Christine Elian and Nil Sanosa and N Bogliotti and Christian Herrero and Diego Sampedro and D L Versace},
title = {Anthraquinone-based oxime ester as visible-light photoinitiator for 3D photoprinting applications},
journal = {Polymer Chemistry},
year = {2023},
volume = {14},
publisher = {Royal Society of Chemistry (RSC)},
month = {jun},
url = {https://xlink.rsc.org/?DOI=D3PY00681F},
number = {28},
pages = {3262--3269},
doi = {10.1039/d3py00681f}
}
MLA
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Elian, Christine, et al. “Anthraquinone-based oxime ester as visible-light photoinitiator for 3D photoprinting applications.” Polymer Chemistry, vol. 14, no. 28, Jun. 2023, pp. 3262-3269. https://xlink.rsc.org/?DOI=D3PY00681F.