Open Access
Chemical Science, volume 14, issue 43, pages 12379-12385
Fluoroalkylated Hypervalent Sulfur Fluorides: Radical Addition of Arylchlorotetrafluoro-λ6-sulfanes to Tetrafluoroethylene
Eisuke Yasuo
1
,
Koichi Mikami
1
,
Kyoko Nozaki
2
,
Takashi Okazoe
1, 3
3
Yokohama Technical Center, AGC Inc., 1-1 Suehiro-cho, Tsurumi-ku, Yokohama 230-0045, Japan
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Publication type: Journal Article
Publication date: 2023-10-19
Journal:
Chemical Science
scimago Q1
SJR: 2.333
CiteScore: 14.4
Impact factor: 7.6
ISSN: 20416520, 20416539
General Chemistry
Abstract
Unprecedented aryl(polyfluoroethyl)tetrafluoro-λ6-sulfanes were synthesized via the radical addition of arylchlorotetrafluoro-λ6-sulfanes to tetrafluoroethylene. The bridging tetrafluoro-λ6-sulfanyl moiety strongly enhanced the hydrophobicity.
Found
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