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Open access
Chemical Science, volume 14, issue 43, pages 12379-12385

Fluoroalkylated Hypervalent Sulfur Fluorides: Radical Addition of Arylchlorotetrafluoro-λ6-sulfanes to Tetrafluoroethylene

Publication typeJournal Article
Publication date2023-10-19
Journal: Chemical Science
scimago Q1
SJR2.333
CiteScore14.4
Impact factor7.6
ISSN20416520, 20416539
General Chemistry
Abstract

Unprecedented aryl(polyfluoroethyl)tetrafluoro-λ6-sulfanes were synthesized via the radical addition of arylchlorotetrafluoro-λ6-sulfanes to tetrafluoroethylene. The bridging tetrafluoro-λ6-sulfanyl moiety strongly enhanced the hydrophobicity.

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