N-Heterocycle-coordinated λ5-iodanes as IBX alternatives for alcohol oxidations
Publication type: Journal Article
Publication date: 2025-01-01
scimago Q1
wos Q2
SJR: 1.037
CiteScore: 7.4
Impact factor: 4.2
ISSN: 13597345, 1364548X
PubMed ID:
39666318
Abstract
We report the synthesis of novel N-coordinated λ5-iodanes as a unique class of hypervalent iodine compounds. X-ray diffraction analysis revealed their intriguing (pseudo)cyclic structure, showcasing distinctive N⋯I-secondary bonding interactions. We demonstrate the in situ generation of reactive diacetoxy derivatives, which exhibits remarkable efficacy in alcohol oxidation reactions. Thermal stability assessments using TGA/DSC analysis provide crucial insights into the handling and potential applications of these compounds. This work expands the frontier of hypervalent iodine chemistry, offering new tools for selective oxidation reactions.
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Total citations:
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Citations from 2025:
2
(100%)
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Antonkin N. S. et al. N-Heterocycle-coordinated λ5-iodanes as IBX alternatives for alcohol oxidations // Chemical Communications. 2025. Vol. 61. No. 4. pp. 756-759.
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Antonkin N. S., Vlasenko Y. A., Puylaert P., Nachtsheim B. J., Postnikov P. S. N-Heterocycle-coordinated λ5-iodanes as IBX alternatives for alcohol oxidations // Chemical Communications. 2025. Vol. 61. No. 4. pp. 756-759.
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RIS
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TY - JOUR
DO - 10.1039/d4cc05058d
UR - https://xlink.rsc.org/?DOI=D4CC05058D
TI - N-Heterocycle-coordinated λ5-iodanes as IBX alternatives for alcohol oxidations
T2 - Chemical Communications
AU - Antonkin, Nikita S
AU - Vlasenko, Yulia A
AU - Puylaert, Pim
AU - Nachtsheim, Boris J
AU - Postnikov, Pavel S.
PY - 2025
DA - 2025/01/01
PB - Royal Society of Chemistry (RSC)
SP - 756-759
IS - 4
VL - 61
PMID - 39666318
SN - 1359-7345
SN - 1364-548X
ER -
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BibTex (up to 50 authors)
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@article{2025_Antonkin,
author = {Nikita S Antonkin and Yulia A Vlasenko and Pim Puylaert and Boris J Nachtsheim and Pavel S. Postnikov},
title = {N-Heterocycle-coordinated λ5-iodanes as IBX alternatives for alcohol oxidations},
journal = {Chemical Communications},
year = {2025},
volume = {61},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://xlink.rsc.org/?DOI=D4CC05058D},
number = {4},
pages = {756--759},
doi = {10.1039/d4cc05058d}
}
Cite this
MLA
Copy
Antonkin, Nikita S., et al. “N-Heterocycle-coordinated λ5-iodanes as IBX alternatives for alcohol oxidations.” Chemical Communications, vol. 61, no. 4, Jan. 2025, pp. 756-759. https://xlink.rsc.org/?DOI=D4CC05058D.
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