Chemical Communications

, том 61 , издание 4 , страницы 756-759

N-Heterocycle-coordinated λ⁵-iodanes as IBX alternatives for alcohol oxidations

Тип публикации: Journal Article

Дата публикации: 2025-01-01

Royal Society of Chemistry (RSC)

Chemical Communications

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wos Q2

БС1

SJR: 1.037

CiteScore: 7.4

Impact factor: 4.2

ISSN: 13597345, 1364548X

DOI: 10.1039/d4cc05058d

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PubMed ID: 39666318

Краткое описание

We report the synthesis of novel N-coordinated λ5-iodanes as a unique class of hypervalent iodine compounds. X-ray diffraction analysis revealed their intriguing (pseudo)cyclic structure, showcasing distinctive N⋯I-secondary bonding interactions. We demonstrate the in situ generation of reactive diacetoxy derivatives, which exhibits remarkable efficacy in alcohol oxidation reactions. Thermal stability assessments using TGA/DSC analysis provide crucial insights into the handling and potential applications of these compounds. This work expands the frontier of hypervalent iodine chemistry, offering new tools for selective oxidation reactions.

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Biotechnology Journal	Biotechnology Journal, 1, 33.33% Biotechnology Journal 1 публикация, 33.33%
Organic Chemistry Frontiers	Organic Chemistry Frontiers, 1, 33.33% Organic Chemistry Frontiers 1 публикация, 33.33%
Organometallics	Organometallics, 1, 33.33% Organometallics 1 публикация, 33.33%
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Wiley	Wiley, 1, 33.33% Wiley 1 публикация, 33.33%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 1, 33.33% Royal Society of Chemistry (RSC) 1 публикация, 33.33%
American Chemical Society (ACS)	American Chemical Society (ACS), 1, 33.33% American Chemical Society (ACS) 1 публикация, 33.33%
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Antonkin N. S. et al. N-Heterocycle-coordinated λ5-iodanes as IBX alternatives for alcohol oxidations // Chemical Communications. 2025. Vol. 61. No. 4. pp. 756-759.

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Antonkin N. S., Vlasenko Y. A., Puylaert P., Nachtsheim B. J., Postnikov P. S. N-Heterocycle-coordinated λ5-iodanes as IBX alternatives for alcohol oxidations // Chemical Communications. 2025. Vol. 61. No. 4. pp. 756-759.

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TY - JOUR

DO - 10.1039/d4cc05058d

UR - https://xlink.rsc.org/?DOI=D4CC05058D

TI - N-Heterocycle-coordinated λ5-iodanes as IBX alternatives for alcohol oxidations

T2 - Chemical Communications

AU - Antonkin, Nikita S

AU - Vlasenko, Yulia A

AU - Puylaert, Pim

AU - Nachtsheim, Boris J

AU - Postnikov, Pavel S.

PY - 2025

DA - 2025/01/01

PB - Royal Society of Chemistry (RSC)

SP - 756-759

IS - 4

VL - 61

PMID - 39666318

SN - 1359-7345

SN - 1364-548X

ER -

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@article{2025_Antonkin,

author = {Nikita S Antonkin and Yulia A Vlasenko and Pim Puylaert and Boris J Nachtsheim and Pavel S. Postnikov},

title = {N-Heterocycle-coordinated λ5-iodanes as IBX alternatives for alcohol oxidations},

journal = {Chemical Communications},

year = {2025},

volume = {61},

publisher = {Royal Society of Chemistry (RSC)},

month = {jan},

url = {https://xlink.rsc.org/?DOI=D4CC05058D},

number = {4},

pages = {756--759},

doi = {10.1039/d4cc05058d}

}

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Antonkin, Nikita S., et al. “N-Heterocycle-coordinated λ5-iodanes as IBX alternatives for alcohol oxidations.” Chemical Communications, vol. 61, no. 4, Jan. 2025, pp. 756-759. https://xlink.rsc.org/?DOI=D4CC05058D.