Catalysis Science and Technology, volume 14, issue 14, pages 3984-3995
Penta- versus hexa-coordinated iridium catalysts control the reactivity of the direct reductive amination between aliphatic amines and aliphatic ketones: a DFT-guided mechanism
Hao Lin
1
,
Longfei Li
1
,
Lanbo Liu
1
,
Zhihui Li
1
,
Thi Mo Nguyen
2
,
Matthieu Jouffroy
3
,
3
Chemical Process R&D, Discovery Process Research, Janssen Pharmaceutica N.V, Turnhoutseweg 30, 2340 Beerse, Belgium
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Publication type: Journal Article
Publication date: 2024-06-13
Journal:
Catalysis Science and Technology
scimago Q2
SJR: 1.050
CiteScore: 8.7
Impact factor: 4.4
ISSN: 20444753, 20444761
Abstract
The mechanism of the iridium-catalysed direct reductive amination between aliphatic partners was studied by DFT calculations leading to important changes in the rate-determining step depending on the nature of the ligand coordinating to iridium.
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