Dalton Transactions, volume 53, issue 24, pages 10113-10119

Access to 1,2,3-triphospholide ligands by reduction of di-tert-butyldiphosphatetrahedrane

Publication type: Journal Article
Publication date: 2024-05-08
scimago Q1
SJR: 0.697
CiteScore: 6.6
Impact factor: 3.5
ISSN: 14779226, 14779234
DOI:  10.1039/d4dt01067a
PubMed ID:  38747137
Abstract

The reduction of (tBuCP)2 with alkali metals affords the anion (1,2,3-P3C2tBu2)−. Coordination studies of the anion have yielded organometallic sandwich complexes, while the hexaphosphane tBu4C4P6 was obtained by oxidation.

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