Dalton Transactions, volume 53, issue 35, pages 14875-14886

Selective synthesis of the missing tiara-like Ni₁₀, Ni₅ and Ni₆ thiolates by the C–S bond cleavage of bis(thioether) molecules with a DFT study

Suparno Debnath ¹

Sandip Giri ¹

Ganesan Mani ¹

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Department of Chemistry, Indian Institute of Technology Kharagpur, Kharagpur, 721302 India |

Publication type: Journal Article

Publication date: 2024-08-14

Royal Society of Chemistry (RSC)

Journal: Dalton Transactions

scimago Q1

SJR: 0.697

CiteScore: 6.6

Impact factor: 3.5

ISSN: 14779226, 14779234

DOI: 10.1039/d4dt02047b

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Abstract

The contrasting reactions of a series of new bis(thioether) molecules with nickel salts have led to synthetic methods selective for particular toroidal nickel(ii) thiolates by the C–S bond cleavage with X-ray structures and DFT study.

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Publisher

Royal Society of Chemistry (RSC)

Journal

Dalton Transactions

scimago Q1

SJR

0.697

CiteScore

6.6

Impact factor

3.5

ISSN

14779226 (Print)

14779234 (Electronic)

Selective synthesis of the missing tiara-like Ni10, Ni5 and Ni6 thiolates by the C–S bond cleavage of bis(thioether) molecules with a DFT study

Are you a researcher?

Selective synthesis of the missing tiara-like Ni₁₀, Ni₅ and Ni₆ thiolates by the C–S bond cleavage of bis(thioether) molecules with a DFT study