Royal Society of Chemistry (RSC)
Organic and Biomolecular Chemistry
,  том 22 ,  издание 35 ,  страницы 7121-7127

Directed regioselective arylation of imidazo[1,2-a]pyridine-3-carboxamides using Rh(iii) catalysis

Kousar Jahan 1, 2
, 
Mehak Sood 1
, 
Osheen Jain 1
, 
Subash Chandra Sahoo 3
, 
Prasad V. Bharatam 1
1
 
Department of Medicinal Chemistry, National Institute of Pharmaceutical Education and Research (NIPER), Sector 67, S. A. S. Nagar, Punjab, India | 
2
 
Lloyd Institute of Management and Technology, Plot No.-3, Knowledge Park-II, Greater Noida, Uttar Pradesh, India-201306 | 
3
 
Тип публикации: Journal Article
Дата публикации: 2024-08-12
Royal Society of Chemistry (RSC)
scimago Q2
wos Q2
БС1
SJR: 0.600
CiteScore: 5.2
Impact factor: 2.7
ISSN: 14770520, 14770539
Краткое описание
In contrast to previously reported free-radical pathways to functionalize imidazo[1,2-a]pyridines at the C-5 centre, directing group approaches are rare. Herein, we demonstrate a rhodium(III) catalyzed efficient and regioselective strategy for directed C-5 functionalization of imidazo[1,2-a]pyridines using N-methoxyamide as a directing group. This methodology facilitates directed arylation without the necessity for pre-functionalization. It also allows for gram-scale synthesis and post-functionalization.
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Bioorganic and Medicinal Chemistry
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Jahan K. et al. Directed regioselective arylation of imidazo[1,2-a]pyridine-3-carboxamides using Rh(iii) catalysis // Organic and Biomolecular Chemistry. 2024. Vol. 22. No. 35. pp. 7121-7127.
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Jahan K., Sood M., Jain O., Chandra Sahoo S., Bharatam P. V. Directed regioselective arylation of imidazo[1,2-a]pyridine-3-carboxamides using Rh(iii) catalysis // Organic and Biomolecular Chemistry. 2024. Vol. 22. No. 35. pp. 7121-7127.
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TY - JOUR
DO - 10.1039/d4ob01166j
UR - https://xlink.rsc.org/?DOI=D4OB01166J
TI - Directed regioselective arylation of imidazo[1,2-a]pyridine-3-carboxamides using Rh(iii) catalysis
T2 - Organic and Biomolecular Chemistry
AU - Jahan, Kousar
AU - Sood, Mehak
AU - Jain, Osheen
AU - Chandra Sahoo, Subash
AU - Bharatam, Prasad V.
PY - 2024
DA - 2024/08/12
PB - Royal Society of Chemistry (RSC)
SP - 7121-7127
IS - 35
VL - 22
PMID - 39155840
SN - 1477-0520
SN - 1477-0539
ER -
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@article{2024_Jahan,
author = {Kousar Jahan and Mehak Sood and Osheen Jain and Subash Chandra Sahoo and Prasad V. Bharatam},
title = {Directed regioselective arylation of imidazo[1,2-a]pyridine-3-carboxamides using Rh(iii) catalysis},
journal = {Organic and Biomolecular Chemistry},
year = {2024},
volume = {22},
publisher = {Royal Society of Chemistry (RSC)},
month = {aug},
url = {https://xlink.rsc.org/?DOI=D4OB01166J},
number = {35},
pages = {7121--7127},
doi = {10.1039/d4ob01166j}
}
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Jahan, Kousar, et al. “Directed regioselective arylation of imidazo[1,2-a]pyridine-3-carboxamides using Rh(iii) catalysis.” Organic and Biomolecular Chemistry, vol. 22, no. 35, Aug. 2024, pp. 7121-7127. https://xlink.rsc.org/?DOI=D4OB01166J.