Organic Chemistry Frontiers, volume 11, issue 8, pages 2178-2181

Synthesis of Enantiopure 1,2,3-Triazolylidene-Type Mesoionic Carbenes (MICs) Conjugate Acids Featuring a Rigid Bicyclic Scaffold

Vojtěch Dočekal ^{1, 2}

Mohand Melaimi ²

Simona Petrželová ³

Jan Veselý ¹

Xiaoyu Yan ⁴

Gilles Bertrand ²

Department of Organic Chemistry, Faculty of Science, Charles University, Hlavova 2030/8, 128 43 Prague 2, Czech Republic |

UCSD-CNRS Joint Research Laboratory (IRL3555), Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, CA-92093-0343, USA |

Department of Chemistry Education, Faculty of Science, Charles University, Hlavova 2030/8, 128 43 Prague 2, Czech Republic |

⁴

Key Laboratory of Advanced Light Conversion Materials and Biophotonics, Department of Chemistry, Renmin University of China, Beijing, 100872, China |

Publication type: Journal Article

Publication date: 2024-02-20

Royal Society of Chemistry (RSC)

Journal: Organic Chemistry Frontiers

scimago Q1

SJR: 1.016

CiteScore: 7.8

Impact factor: 4.6

ISSN: 20524110, 20524129

DOI: 10.1039/d4qo00269e

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Organic Chemistry

Abstract

Chiral NHCs have found numerous applications as ligands for transition metals and in their own right for asymmetric catalysis. We report a synthetic route from l-malic acid to enantiopure 1,2,3-triazoliums with the chiral center in a fused ring.

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Publisher

Royal Society of Chemistry (RSC)

Journal

Organic Chemistry Frontiers

scimago Q1

SJR

1.016

CiteScore

7.8

Impact factor

4.6

ISSN

20524110 (Print)

20524129 (Electronic)

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